A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Acceptor Copolymerized Axially Chiral Conjugated Polymers with TADF Properties for Efficient Circularly Polarized Electroluminescence
Chiral conjugated polymer has promoted the development of the efficient circularly polarized electroluminescence (CPEL) device, nevertheless, it remains a challenge to develop chiral polymers with high electroluminescence performance. Herein, by the acceptor copolymerization of axially chiral biphenyl emitting skeleton and benzophenone, a pair of axially chiral conjugated polymers namely R‐PAC and S‐PAC are synthesized. The target polymers exhibit obvious thermally activated delayed fluorescence (TADF) activities with high photoluminescence quantum yields of 81%. Moreover, the chiral polymers display significant circularly polarized luminescence features, with luminescence dissymmetry factor (|glum|) of nearly 3 × 10−3. By using the chiral polymers as emitters, the corresponding circularly polarized organic light‐emitting diodes (CP‐OLEDs) exhibit efficient CPEL signals with electroluminescence dissymmetry factor |gEL| of 3.4 × 10−3 and high maximum external quantum efficiency (EQEmax) of 17.8%. Notably, considering both EQEmax and |gEL| comprehensively, the device performance of R‐PAC and S‐PAC is the best among all the reported CP‐OLEDs with chiral conjugated polymers as emitters. This work provides a facile approach to constructing chiral conjugated TADF polymers and discloses the potential of axially chiral conjugated luminescent skeletons in architecting high‐performance CP‐OLEDs.
Acceptor Copolymerized Axially Chiral Conjugated Polymers with TADF Properties for Efficient Circularly Polarized Electroluminescence
Chiral conjugated polymer has promoted the development of the efficient circularly polarized electroluminescence (CPEL) device, nevertheless, it remains a challenge to develop chiral polymers with high electroluminescence performance. Herein, by the acceptor copolymerization of axially chiral biphenyl emitting skeleton and benzophenone, a pair of axially chiral conjugated polymers namely R‐PAC and S‐PAC are synthesized. The target polymers exhibit obvious thermally activated delayed fluorescence (TADF) activities with high photoluminescence quantum yields of 81%. Moreover, the chiral polymers display significant circularly polarized luminescence features, with luminescence dissymmetry factor (|glum|) of nearly 3 × 10−3. By using the chiral polymers as emitters, the corresponding circularly polarized organic light‐emitting diodes (CP‐OLEDs) exhibit efficient CPEL signals with electroluminescence dissymmetry factor |gEL| of 3.4 × 10−3 and high maximum external quantum efficiency (EQEmax) of 17.8%. Notably, considering both EQEmax and |gEL| comprehensively, the device performance of R‐PAC and S‐PAC is the best among all the reported CP‐OLEDs with chiral conjugated polymers as emitters. This work provides a facile approach to constructing chiral conjugated TADF polymers and discloses the potential of axially chiral conjugated luminescent skeletons in architecting high‐performance CP‐OLEDs.
Acceptor Copolymerized Axially Chiral Conjugated Polymers with TADF Properties for Efficient Circularly Polarized Electroluminescence
Zhao, Wen‐Long (author) / Tan, Ke‐Ke (author) / Guo, Wei‐Chen (author) / Guo, Chen‐Hao (author) / Li, Meng (author) / Chen, Chuan‐Feng (author)
Advanced Science ; 11
2024-06-01
9 pages
Article (Journal)
Electronic Resource
English
Circularly Polarized Electroluminescence from Liquid-Crystalline Chiral Polyfluorenes
| British Library Online Contents | 2000
Highly Circularly Polarized Electroluminescence from a Chiral Europium Complex
| British Library Online Contents | 2015
| Wiley | 2024
| Wiley | 2024