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Experimental Investigation of the Reaction Network of Ethene to Propene over Ni/AlMCM‐41 Catalysts

Perea, Leo Alvarado / Felischak, Matthias / Wolff, Tanya / Hamel, Christof / Seidel‐Morgenstern, Andreas

The reaction network of the ethene‐to‐propene (ETP) reaction over Ni/AlMCM‐41 catalysts was studied. This reaction consists of the dimerization of ethene, the isomerization of 1‐butene, and the metathesis of ethene and 2‐butene to propene. This work focused on the latter. ETP experiments followed by in situ diffuse reflectance infrared Fourier transform spectroscopy were carried out. Metathesis activities were evaluated by the isomerization of butenes, the metathesis of ethene and 2‐butene, and the retro‐metathesis of propene. Metathesis activities of Ni/AlMCM‐41 catalysts were not observed. Thus, a conjunct polymerization of ethene to propene is proposed.

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Experimental Investigation of the Reaction Network of Ethene to Propene over Ni/AlMCM‐41 Catalysts

Perea, Leo Alvarado / Felischak, Matthias / Wolff, Tanya / Hamel, Christof / Seidel‐Morgenstern, Andreas

The reaction network of the ethene‐to‐propene (ETP) reaction over Ni/AlMCM‐41 catalysts was studied. This reaction consists of the dimerization of ethene, the isomerization of 1‐butene, and the metathesis of ethene and 2‐butene to propene. This work focused on the latter. ETP experiments followed by in situ diffuse reflectance infrared Fourier transform spectroscopy were carried out. Metathesis activities were evaluated by the isomerization of butenes, the metathesis of ethene and 2‐butene, and the retro‐metathesis of propene. Metathesis activities of Ni/AlMCM‐41 catalysts were not observed. Thus, a conjunct polymerization of ethene to propene is proposed.

Experimental Investigation of the Reaction Network of Ethene to Propene over Ni/AlMCM‐41 Catalysts

Perea, Leo Alvarado / Felischak, Matthias / Wolff, Tanya / Hamel, Christof / Seidel‐Morgenstern, Andreas

The reaction network of the ethene‐to‐propene (ETP) reaction over Ni/AlMCM‐41 catalysts was studied. This reaction consists of the dimerization of ethene, the isomerization of 1‐butene, and the metathesis of ethene and 2‐butene to propene. This work focused on the latter. ETP experiments followed by in situ diffuse reflectance infrared Fourier transform spectroscopy were carried out. Metathesis activities were evaluated by the isomerization of butenes, the metathesis of ethene and 2‐butene, and the retro‐metathesis of propene. Metathesis activities of Ni/AlMCM‐41 catalysts were not observed. Thus, a conjunct polymerization of ethene to propene is proposed.

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Title:

Experimental Investigation of the Reaction Network of Ethene to Propene over Ni/AlMCM‐41 Catalysts

Contributors:

Perea, Leo Alvarado (author) / Felischak, Matthias (author) / Wolff, Tanya (author) / Hamel, Christof (author) / Seidel‐Morgenstern, Andreas (author)

Published in:

Chemie Ingenieur Technik ; 89 ; 903-914

Publication date:

2017-07-01

Size:

12 pages

ISSN:

0009-286X , 1522-2640

DOI:

https://doi.org/10.1002/cite.201600166

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Propene , Ethene , Ni/AlMCM‐41 catalysts , Metathesis , Reaction network

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