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Electrokinetic Removal of Petroleum Hydrocarbon from Residual Clayey Soil Following a Washing Process
10.1002/clen.200900190.abs
This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO4 or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO4. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO4and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.
Electrokinetic Removal of Petroleum Hydrocarbon from Residual Clayey Soil Following a Washing Process
10.1002/clen.200900190.abs
This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO4 or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO4. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO4and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.
Electrokinetic Removal of Petroleum Hydrocarbon from Residual Clayey Soil Following a Washing Process
Jeon, Chil‐Sung (author) / Yang, Jung‐Seok (author) / Kim, Kyung‐Jo (author) / Baek, Kitae (author)
CLEAN – Soil, Air, Water ; 38 ; 189-193
2010-02-01
5 pages
Article (Journal)
Electronic Resource
English
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