A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Complexes of N‐Confused Porphyrin Derivatives as Ortho‐Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality
A family of transition metal complexes of meso‐aryl‐2‐aza‐21‐carbaporphyrin (N‐confused porphyrin, NCP) derivatives acting as ortho‐metallating ligands for ruthenium(II), rhodium(III), and iridium(III) is synthesized and characterized by XRD, spectroscopic, and electrochemical methods. The chirality of these systems is shown by the separation of the enantiomers and analyzed by circular dichroism and DFT. A preliminary catalytic study indicates the activity of the iridium(III) ortho‐metallated complexes in the N‐heterocyclization of primary amines with diols.
Complexes of N‐Confused Porphyrin Derivatives as Ortho‐Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality
A family of transition metal complexes of meso‐aryl‐2‐aza‐21‐carbaporphyrin (N‐confused porphyrin, NCP) derivatives acting as ortho‐metallating ligands for ruthenium(II), rhodium(III), and iridium(III) is synthesized and characterized by XRD, spectroscopic, and electrochemical methods. The chirality of these systems is shown by the separation of the enantiomers and analyzed by circular dichroism and DFT. A preliminary catalytic study indicates the activity of the iridium(III) ortho‐metallated complexes in the N‐heterocyclization of primary amines with diols.
Complexes of N‐Confused Porphyrin Derivatives as Ortho‐Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality
Koniarz, Sebastian (author) / Szydełko, Kinga (author) / Białek, Michał J. (author) / Hurej, Karolina (author) / Chmielewski, Piotr J. (author)
Advanced Science ; 11
2024-01-01
15 pages
Article (Journal)
Electronic Resource
English
| Online Contents | 1995
| British Library Online Contents | 1995
The 1981 Wiring Rules - are you confused?
| Tema Archive | 1982