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A modeling approach for VOC emissions from sewers
ABSTRACT: Experimental and computational studies were completed to assess volatile organic compound (VOC) emissions from wastewater collection systems. Deuterated chloroform solutions were released into two operating collection systems as a VOC tracer. Downstream sampling of the sewer headspace and wastewater was performed and samples were analyzed by mass spectrometry. Results were used to evaluate a twophase finite volume model for VOC interphase mass transfer and emissions for uniform reaches in sewers. Differences between predicted and experimental average steady‐state concentrations were less than 30%, quite adequate for emission estimation purposes given other uncertainties in wastewater characteristics. The model described in this paper is intended to serve as a screening tool to identify conditions leading to emissions of VOCs from collection systems. The modeling approach can also serve as a basis for more advanced computational solutions as the knowledge base associated with VOCs in sewers improves.
A modeling approach for VOC emissions from sewers
ABSTRACT: Experimental and computational studies were completed to assess volatile organic compound (VOC) emissions from wastewater collection systems. Deuterated chloroform solutions were released into two operating collection systems as a VOC tracer. Downstream sampling of the sewer headspace and wastewater was performed and samples were analyzed by mass spectrometry. Results were used to evaluate a twophase finite volume model for VOC interphase mass transfer and emissions for uniform reaches in sewers. Differences between predicted and experimental average steady‐state concentrations were less than 30%, quite adequate for emission estimation purposes given other uncertainties in wastewater characteristics. The model described in this paper is intended to serve as a screening tool to identify conditions leading to emissions of VOCs from collection systems. The modeling approach can also serve as a basis for more advanced computational solutions as the knowledge base associated with VOCs in sewers improves.
A modeling approach for VOC emissions from sewers
Corsi, Richard L. (author) / Chang, Daniel P. Y. (author) / Schroeder, Edward D. (author)
Water Environment Research ; 64 ; 734-741
1992-07-01
8 pages
Article (Journal)
Electronic Resource
English
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