Application of zeolitic imidazolate framework for hexavalent chromium removal: A feasibility and mechanism study: Fid-Bau Portal

Application of zeolitic imidazolate framework for hexavalent chromium removal: A feasibility and mechanism study

Ou, Jiun‐Hau / Sheu, Yih‐Terng / Chang, Bor Kae / Verpoort, Francis / Surampalli, Rao Y. / Kao, Chih‐Ming

The mechanisms and effectiveness of using zeolitic imidazolate framework (ZIF‐8) [a sub‐family of metal‐organic framework (MOF)] particles on hexavalent chromium [Cr(VI)] removal were evaluated. The ultrasonic mixing method was applied for the preparation of ZIF‐8, and chemicals used for ZIF‐8 synthesis included ammonium hydroxide, zinc nitrate hexahydrate, and 2‐methylimidazole. ZIF‐8 particle had a clear rhombic dodecahedron morphology shape and a strong peak intensity with high crystallinity. The adsorption capacity (AC) of ZIF‐8 was 30.3 mg of Cr(VI)/g of ZIF‐8 [Cr(VI) = 50 mg/L]. The AC of Cr(VI) raised to 34.3 mg/g under acidic conditions (pH = 5), and the AC dropped to below 13.7 mg/g with a pH range from 7 to 11. It could be because of the competitive effects between CrO₄²⁻ and hydroxide ions for adsorption locations of ZIF‐8. Cr(VI) removal relied on the amount of Cr(VI) adsorbed on the particles of ZIF‐8, and the mechanisms of Cr(VI) adsorption by ZIF‐8 included chemical/physical processes and the rate‐limiting step was the chemical adsorption. A fraction of sorbed Cr(VI) was reduced to Cr(III), and thus, ZIF‐8 could serve as a reducing agent during Cr(VI) reduction. Cr(VI) was removed effectively from the water phase by ZIF‐8 via adsorption and reduction mechanisms.

ZIF‐8 particles had an adsorption capacity of 30.33 mg of Cr(VI)/g of ZIF‐8. Cr(VI) sorption by ZIF‐8 has chemical (rate‐limiting step) and physical processes. ZIF‐8 can serve as a reducing agent for Cr(VI) reduction. Cr(VI) can be removed by ZIF‐8 via the adsorption and reduction mechanisms.