Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Eine Plattform für die Wissenschaft: Bauingenieurwesen, Architektur und Urbanistik
Kinetics of interaction of hydroperoxides with some disulphides
Abstract Disulphides catalytically break down tert-butyl and cumyl hydroperoxides. In chlorobenzene breakdown takes place by a bimolecular mechanism at a rate which is directly proportional to the concentration of hydroperoxide and disulphide; the rate constant of this reaction varies from 0·4 to 1·21.mole · sec at 373°K for disulphides and tert-butyl hydroperoxide, respectively. No radicals are formed by the reaction of tert-butyl hydroperoxide with disulphide.
Kinetics of interaction of hydroperoxides with some disulphides
Abstract Disulphides catalytically break down tert-butyl and cumyl hydroperoxides. In chlorobenzene breakdown takes place by a bimolecular mechanism at a rate which is directly proportional to the concentration of hydroperoxide and disulphide; the rate constant of this reaction varies from 0·4 to 1·21.mole · sec at 373°K for disulphides and tert-butyl hydroperoxide, respectively. No radicals are formed by the reaction of tert-butyl hydroperoxide with disulphide.
Kinetics of interaction of hydroperoxides with some disulphides
Aslanov, A.D. (Autor:in) / Zolotova, N.V. (Autor:in) / Denisov, Ye.T. (Autor:in) / Kuliyev, F.A. (Autor:in)
01.01.1983
7 pages
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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