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Kinetics of interaction of hydroperoxides with some disulphides
Abstract Disulphides catalytically break down tert-butyl and cumyl hydroperoxides. In chlorobenzene breakdown takes place by a bimolecular mechanism at a rate which is directly proportional to the concentration of hydroperoxide and disulphide; the rate constant of this reaction varies from 0·4 to 1·21.mole · sec at 373°K for disulphides and tert-butyl hydroperoxide, respectively. No radicals are formed by the reaction of tert-butyl hydroperoxide with disulphide.
Kinetics of interaction of hydroperoxides with some disulphides
Abstract Disulphides catalytically break down tert-butyl and cumyl hydroperoxides. In chlorobenzene breakdown takes place by a bimolecular mechanism at a rate which is directly proportional to the concentration of hydroperoxide and disulphide; the rate constant of this reaction varies from 0·4 to 1·21.mole · sec at 373°K for disulphides and tert-butyl hydroperoxide, respectively. No radicals are formed by the reaction of tert-butyl hydroperoxide with disulphide.
Kinetics of interaction of hydroperoxides with some disulphides
Aslanov, A.D. (author) / Zolotova, N.V. (author) / Denisov, Ye.T. (author) / Kuliyev, F.A. (author)
1983-01-01
7 pages
Article (Journal)
Electronic Resource
English
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