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Interaction of organo-sulphur compounds with iron carbonyls

Nametkin, N.S. / Tyurin, V.D. / Gubin, S.P. / Kukina, M.A.

Abstract 1. 1. Reactions of organo-sulphur compounds (mercaptans, di-sulphides and sulphides) with iron penta-, nona- and dodecacarbonyls were examined. In reactivity organo-sulphur compounds and iron carbonyls occupy the following order: RSH>RSSR>RSR; Fe3(CO)12>Fe2(CO)9>Fe(CO)5. 2. 2. A new method is proposed for the synthesis of bis-(alkylthio-iron tricarbonyl) using the triethylammonium salt of tri-iron-undecacarbonyl.

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Interaction of organo-sulphur compounds with iron carbonyls

Nametkin, N.S. / Tyurin, V.D. / Gubin, S.P. / Kukina, M.A.

Abstract 1. 1. Reactions of organo-sulphur compounds (mercaptans, di-sulphides and sulphides) with iron penta-, nona- and dodecacarbonyls were examined. In reactivity organo-sulphur compounds and iron carbonyls occupy the following order: RSH>RSSR>RSR; Fe3(CO)12>Fe2(CO)9>Fe(CO)5. 2. 2. A new method is proposed for the synthesis of bis-(alkylthio-iron tricarbonyl) using the triethylammonium salt of tri-iron-undecacarbonyl.

Interaction of organo-sulphur compounds with iron carbonyls

Nametkin, N.S. / Tyurin, V.D. / Gubin, S.P. / Kukina, M.A.

Abstract 1. 1. Reactions of organo-sulphur compounds (mercaptans, di-sulphides and sulphides) with iron penta-, nona- and dodecacarbonyls were examined. In reactivity organo-sulphur compounds and iron carbonyls occupy the following order: RSH>RSSR>RSR; Fe3(CO)12>Fe2(CO)9>Fe(CO)5. 2. 2. A new method is proposed for the synthesis of bis-(alkylthio-iron tricarbonyl) using the triethylammonium salt of tri-iron-undecacarbonyl.

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Titel:

Interaction of organo-sulphur compounds with iron carbonyls

Beteiligte:

Nametkin, N.S. (Autor:in) / Tyurin, V.D. (Autor:in) / Gubin, S.P. (Autor:in) / Kukina, M.A. (Autor:in)

Erschienen in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 15 ; 177-181

Erscheinungsdatum:

25.04.1975

Format / Umfang:

5 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(75)90026-X

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

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