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Interaction of organo-sulphur compounds with iron carbonyls
Abstract 1. Reactions of organo-sulphur compounds (mercaptans, di-sulphides and sulphides) with iron penta-, nona- and dodecacarbonyls were examined. In reactivity organo-sulphur compounds and iron carbonyls occupy the following order: RSH>RSSR>RSR; Fe3(CO)12>Fe2(CO)9>Fe(CO)5. 2. A new method is proposed for the synthesis of bis-(alkylthio-iron tricarbonyl) using the triethylammonium salt of tri-iron-undecacarbonyl.
Interaction of organo-sulphur compounds with iron carbonyls
Abstract 1. Reactions of organo-sulphur compounds (mercaptans, di-sulphides and sulphides) with iron penta-, nona- and dodecacarbonyls were examined. In reactivity organo-sulphur compounds and iron carbonyls occupy the following order: RSH>RSSR>RSR; Fe3(CO)12>Fe2(CO)9>Fe(CO)5. 2. A new method is proposed for the synthesis of bis-(alkylthio-iron tricarbonyl) using the triethylammonium salt of tri-iron-undecacarbonyl.
Interaction of organo-sulphur compounds with iron carbonyls
Nametkin, N.S. (author) / Tyurin, V.D. (author) / Gubin, S.P. (author) / Kukina, M.A. (author)
1975-04-25
5 pages
Article (Journal)
Electronic Resource
English