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Flashing ink for ceramic ink-jet printing as well as preparation method and application of flashing ink
The invention relates to the technical field of ceramic ink-jet printing, and provides flash ink for ceramic ink-jet printing as well as a preparation method and application of the flash ink. The formula of the flash ink comprises 40-60 wt% of flash frit powder, 40-60 wt% of an ester solvent, 3-8 wt% of a dispersant and 0-1 wt% of an additive, the formula of the flash frit powder comprises 0 to 19 wt% of wollastonite, 0 to 13 wt% of albite, 0 to 32 wt% of burnt soil, 0 to 5 wt% of dolomite, 3 to 8 wt% of zircon sand, 0.5 to 8 wt% of raw zinc, 16 to 43 wt% of quartz, 7.5 to 12 wt% of cerium nitrate hexahydrate, 0.24 to 0.96 wt% of praseodymium nitrate hexahydrate, 0.5 to 3.5 wt% of boric acid, 0 to 2 wt% of talc, 0 to 6 wt% of nepheline, 0 to 12 wt% of calcined alumina and 0 to 11 wt% of calcite. Wherein the contents of wollastonite and calcite are not 0 at the same time, the contents of albite and nepheline are not 0 at the same time, the contents of burnt soil and calcined alumina are not 0 at the same time, and the contents of dolomite and talc are not 0 at the same time; the mass ratio of praseodymium nitrate hexahydrate to cerium nitrate hexahydrate is not greater than 0.08. The flash ink is subjected to ink-jet printing and low-temperature rapid firing, so that the ceramic tile can obtain a colorful flash effect with bright color, high brightness and high flash, the pattern is not dispersed, and the color is uniform.
本发明涉及陶瓷喷墨打印技术领域,提供一种陶瓷喷墨打印用闪光墨水及其制备方法和应用。该闪光墨水的配方为:闪光熔块粉体40~60wt%、酯类溶剂40~60wt%、分散剂3~8wt%、添加剂0~1wt%;闪光熔块粉体的配方为:硅灰石0~19wt%、钠长石0~13wt%、烧土0~32wt%、白云石0~5wt%、锆英沙3~8wt%、生锌0.5~8wt%、石英16~43wt%、六水硝酸铈7.5~12wt%、六水硝酸镨0.24~0.96wt%、硼酸0.5~3.5wt%、滑石0~2wt%、霞石0~6wt%、煅烧氧化铝0~12wt%、方解石0~11wt%;其中,硅灰石与方解石的含量不同时为0,钠长石与霞石的含量不同时为0,烧土与煅烧氧化铝的含量不同时为0,白云石与滑石的含量不同时为0;六水硝酸镨与六水硝酸铈的质量比不大于0.08。该闪光墨水经喷墨打印及较低温快速烧成,即可使陶瓷砖获得颜色鲜明、高亮高闪且带多彩的闪光效果,且图案不散墨、颜色均匀。
Flashing ink for ceramic ink-jet printing as well as preparation method and application of flashing ink
The invention relates to the technical field of ceramic ink-jet printing, and provides flash ink for ceramic ink-jet printing as well as a preparation method and application of the flash ink. The formula of the flash ink comprises 40-60 wt% of flash frit powder, 40-60 wt% of an ester solvent, 3-8 wt% of a dispersant and 0-1 wt% of an additive, the formula of the flash frit powder comprises 0 to 19 wt% of wollastonite, 0 to 13 wt% of albite, 0 to 32 wt% of burnt soil, 0 to 5 wt% of dolomite, 3 to 8 wt% of zircon sand, 0.5 to 8 wt% of raw zinc, 16 to 43 wt% of quartz, 7.5 to 12 wt% of cerium nitrate hexahydrate, 0.24 to 0.96 wt% of praseodymium nitrate hexahydrate, 0.5 to 3.5 wt% of boric acid, 0 to 2 wt% of talc, 0 to 6 wt% of nepheline, 0 to 12 wt% of calcined alumina and 0 to 11 wt% of calcite. Wherein the contents of wollastonite and calcite are not 0 at the same time, the contents of albite and nepheline are not 0 at the same time, the contents of burnt soil and calcined alumina are not 0 at the same time, and the contents of dolomite and talc are not 0 at the same time; the mass ratio of praseodymium nitrate hexahydrate to cerium nitrate hexahydrate is not greater than 0.08. The flash ink is subjected to ink-jet printing and low-temperature rapid firing, so that the ceramic tile can obtain a colorful flash effect with bright color, high brightness and high flash, the pattern is not dispersed, and the color is uniform.
本发明涉及陶瓷喷墨打印技术领域,提供一种陶瓷喷墨打印用闪光墨水及其制备方法和应用。该闪光墨水的配方为:闪光熔块粉体40~60wt%、酯类溶剂40~60wt%、分散剂3~8wt%、添加剂0~1wt%;闪光熔块粉体的配方为:硅灰石0~19wt%、钠长石0~13wt%、烧土0~32wt%、白云石0~5wt%、锆英沙3~8wt%、生锌0.5~8wt%、石英16~43wt%、六水硝酸铈7.5~12wt%、六水硝酸镨0.24~0.96wt%、硼酸0.5~3.5wt%、滑石0~2wt%、霞石0~6wt%、煅烧氧化铝0~12wt%、方解石0~11wt%;其中,硅灰石与方解石的含量不同时为0,钠长石与霞石的含量不同时为0,烧土与煅烧氧化铝的含量不同时为0,白云石与滑石的含量不同时为0;六水硝酸镨与六水硝酸铈的质量比不大于0.08。该闪光墨水经喷墨打印及较低温快速烧成,即可使陶瓷砖获得颜色鲜明、高亮高闪且带多彩的闪光效果,且图案不散墨、颜色均匀。
Flashing ink for ceramic ink-jet printing as well as preparation method and application of flashing ink
一种陶瓷喷墨打印用闪光墨水及其制备方法和应用
QIN WEI (Autor:in) / YE YOU (Autor:in) / LIU TENG (Autor:in) / ZHOU JUN (Autor:in) / DAI JIANBIN (Autor:in) / HAN YONG (Autor:in) / ZHANG TIANJIE (Autor:in) / ZHAI JIE (Autor:in) / ZHANG DAN (Autor:in)
26.03.2024
Patent
Elektronische Ressource
Chinesisch
Flashing assemblies prepared with liquid flashing compositions
Europäisches Patentamt | 2021
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