Binary mixtures of heavy metal chelates with <Emphasis Type="Italic">N,N,N′,N′</Emphasis>-tetrasubstituted <Emphasis Type="Italic">p</Emphasis>-phenylenediamines in inhibition of ethylbenzene oxidation: Fid-Bau Portal

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Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Mazaletskaya, L. I. / Mazaletskii, A. B.

Abstract Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.

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Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Mazaletskaya, L. I. / Mazaletskii, A. B.

Abstract Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.

Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Mazaletskaya, L. I. / Mazaletskii, A. B.

Abstract Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.

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Titel:

Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Beteiligte:

Mazaletskaya, L. I. (Autor:in) / Mazaletskii, A. B. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 46 ; 269-273

Erscheinungsdatum:

01.07.2006

Format / Umfang:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544106040074

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Phen , Binary Mixture , Petroleum Chemistry , Ethylbenzene , Inhibition Period Chemistry , Industrial Chemistry/Chemical Engineering

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