Binary mixtures of heavy metal chelates with <Emphasis Type="Italic">N,N,N′,N′</Emphasis>-tetrasubstituted <Emphasis Type="Italic">p</Emphasis>-phenylenediamines in inhibition of ethylbenzene oxidation: Fid-Bau Portal

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Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Mazaletskaya, L. I. / Mazaletskii, A. B.

Abstract Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.

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Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Mazaletskaya, L. I. / Mazaletskii, A. B.

Abstract Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.

Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Mazaletskaya, L. I. / Mazaletskii, A. B.

Abstract Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.

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Title:

Binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in inhibition of ethylbenzene oxidation

Contributors:

Mazaletskaya, L. I. (author) / Mazaletskii, A. B. (author)

Published in:

Petroleum Chemistry ; 46 ; 269-273

Publication date:

2006-07-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544106040074

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Phen , Binary Mixture , Petroleum Chemistry , Ethylbenzene , Inhibition Period Chemistry , Industrial Chemistry/Chemical Engineering

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