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Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Khusnutdinov, R. I. / Schchadneva, N. A. / Malikov, A. I. / Dzhemilev, U. M.

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.

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Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Khusnutdinov, R. I. / Schchadneva, N. A. / Malikov, A. I. / Dzhemilev, U. M.

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.

Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Khusnutdinov, R. I. / Schchadneva, N. A. / Malikov, A. I. / Dzhemilev, U. M.

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.

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Titel:

Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Beteiligte:

Khusnutdinov, R. I. (Autor:in) / Schchadneva, N. A. (Autor:in) / Malikov, A. I. (Autor:in) / Dzhemilev, U. M. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 46 ; 159-163

Erscheinungsdatum:

01.05.2006

Format / Umfang:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544106030030

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

Ruthenium , Alkylation , Halide , Adamantane , Alkyl Halide Chemistry , Industrial Chemistry/Chemical Engineering

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