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Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Khusnutdinov, R. I. / Schchadneva, N. A. / Malikov, A. I. / Dzhemilev, U. M.

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.

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Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Khusnutdinov, R. I. / Schchadneva, N. A. / Malikov, A. I. / Dzhemilev, U. M.

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.

Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Khusnutdinov, R. I. / Schchadneva, N. A. / Malikov, A. I. / Dzhemilev, U. M.

Abstract The feasibility of catalytic alkylation of adamantane and 1-bromoadamantane with alkyl halides in the presence of ruthenium-containing catalysts was revealed. The optimum molar ratios between the catalyst components and the reactants, as well as the reaction conditions for the selective synthesis of mono-and dialkylsubstituted adamantane derivatives with a 70–98% yield, were determined.

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Title:

Alkylation of adamantane with alkyl halides catalyzed by ruthenium complexes

Contributors:

Khusnutdinov, R. I. (author) / Schchadneva, N. A. (author) / Malikov, A. I. (author) / Dzhemilev, U. M. (author)

Published in:

Petroleum Chemistry ; 46 ; 159-163

Publication date:

2006-05-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544106030030

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Ruthenium , Alkylation , Halide , Adamantane , Alkyl Halide Chemistry , Industrial Chemistry/Chemical Engineering

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