Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates: Fid-Bau Portal

Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates

Naranov, E. R. / Golubev, O. V. / Guseva, A. I. / Nikulshin, P. A. / Maksimov, A. L. / Karakhanov, E. A.

Abstract The effect of the impregnation stage on the synthesis of NiW sulfide catalysts supported on the ZSM-5 zeolite has been studied. The hydrodearomatization (HDA) of light cycle oil (LCO) in the presence of a catalyst containing nickel and tungsten sulfides as an active phase impregnated onto a micro/mesoporous ZSM-5/SBA-15 support has been conducted. The catalyst has been compared with a commercial AGKD-400 diesel hydrotreating catalyst. It has been found that the impregnation of the supports with a solution containing an oxalic acid additive leads to an improvement in the morphology and composition of the active phase. The deepest hydrogenation is observed at 360°C, 6 MPa H2, and a LHSV = 0.5 h–1. The amount of diaromatic hydrocarbons decreases 12-fold, and the sulfur content decreases by 90%.

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Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates

Naranov, E. R. / Golubev, O. V. / Guseva, A. I. / Nikulshin, P. A. / Maksimov, A. L. / Karakhanov, E. A.

Abstract

Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates

Naranov, E. R. / Golubev, O. V. / Guseva, A. I. / Nikulshin, P. A. / Maksimov, A. L. / Karakhanov, E. A.

Abstract

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Titel:

Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates

Beteiligte:

Naranov, E. R. (Autor:in) / Golubev, O. V. (Autor:in) / Guseva, A. I. (Autor:in) / Nikulshin, P. A. (Autor:in) / Maksimov, A. L. (Autor:in) / Karakhanov, E. A. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 57 ; 1151-1155

Erscheinungsdatum:

01.12.2017

Format / Umfang:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544117060226

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

hydrogenation , hydrodearomatization , hydrotreating , sulfide catalysts , Ni–W , zeolites , micro/mesoporous supports , ZSM-5/SBA-15 Chemistry , Industrial Chemistry/Chemical Engineering

Nikul’shina, M. S. / Mozhaev, A. V. / Lancelot, C. et al. | Springer Verlag | 2019

Hydrogenation of aromatic hydrocarbons over nickel–tungsten sulfide catalysts containing mesoporous aluminosilicates of different nature

Naranov, E. R. / Badeeva, A. S. / Sadovnikov, A. A. et al. | Springer Verlag | 2016

Hydroisomerization of n-dodecane on bifunctional catalysts containing mesoporous aluminosilicates

Karakhanov, E. A. / Kardashev, S. V. / Maksimov, A. L. et al. | Springer Verlag | 2012

Conversions of ethylene and n-butenes using amorphous and crystalline aluminosilicates containing nickel

Lapidus, A.L / Avetisyan, R.V / Isakov, Ya.I et al. | Elsevier | 1969

Cracking of iso-octane on crystalline and amorphous aluminosilicates

Yushchenko, V.V. / Topchiyeva, K.V. / Imanov, F.M. et al. | Elsevier | 1978

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