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Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Tarkhanova, I. G. / Anisimov, A. V. / Verzhichinskaya, S. V. / Buryak, A. K. / Zelikman, V. M. / Gantman, M. G.

Abstract The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.

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Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Tarkhanova, I. G. / Anisimov, A. V. / Verzhichinskaya, S. V. / Buryak, A. K. / Zelikman, V. M. / Gantman, M. G.

Abstract The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.

Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Tarkhanova, I. G. / Anisimov, A. V. / Verzhichinskaya, S. V. / Buryak, A. K. / Zelikman, V. M. / Gantman, M. G.

Abstract The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.

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Titel:

Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Beteiligte:

Tarkhanova, I. G. (Autor:in) / Anisimov, A. V. (Autor:in) / Verzhichinskaya, S. V. (Autor:in) / Buryak, A. K. (Autor:in) / Zelikman, V. M. (Autor:in) / Gantman, M. G. (Autor:in)

Erschienen in:

Petroleum Chemistry ; 56 ; 158-165

Erscheinungsdatum:

01.02.2016

Format / Umfang:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544116020158

Medientyp:

Aufsatz (Zeitschrift)

Format:

Elektronische Ressource

Sprache:

Englisch

Schlagwörter:

metal-containing ionic liquids , immobilized catalysts , oxidation , sulfides Chemistry , Industrial Chemistry/Chemical Engineering

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