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Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Tarkhanova, I. G. / Anisimov, A. V. / Verzhichinskaya, S. V. / Buryak, A. K. / Zelikman, V. M. / Gantman, M. G.

Abstract The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.

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Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Tarkhanova, I. G. / Anisimov, A. V. / Verzhichinskaya, S. V. / Buryak, A. K. / Zelikman, V. M. / Gantman, M. G.

Abstract The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.

Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Tarkhanova, I. G. / Anisimov, A. V. / Verzhichinskaya, S. V. / Buryak, A. K. / Zelikman, V. M. / Gantman, M. G.

Abstract The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.

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Title:

Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides

Contributors:

Tarkhanova, I. G. (author) / Anisimov, A. V. (author) / Verzhichinskaya, S. V. (author) / Buryak, A. K. (author) / Zelikman, V. M. (author) / Gantman, M. G. (author)

Published in:

Petroleum Chemistry ; 56 ; 158-165

Publication date:

2016-02-01

Size:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544116020158

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

metal-containing ionic liquids , immobilized catalysts , oxidation , sulfides Chemistry , Industrial Chemistry/Chemical Engineering

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