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Spectroscopic ellipsometry studies on optical constants of crystalline wax-doped asphalt binders
Asphalt pavement possesses the characteristics of strong sunlight absorption, which lead to the aging of asphalt binder. Asphalt aging is one of the leading causes of the performance deterioration in the asphalt pavement, and the appearance of crystalline wax (paraffin wax) during aging has a significant effect on optical properties (absorption and reflection) of the asphalt binder. In this paper, effects of the crystalline wax on optical properties of the asphalt binder were investigated using the spectroscopic ellipsometry (SE) technique, and a new method for the quantification of the crystalline wax in asphalt was also developed. Cold Lake asphalt doped with different contents of n-alkanes (eicosane, triacontane, and tetracontane) were tested by the SE. The results showed that there is a close linear relationship between the optical constants and wax content of the asphalt binder. In addition, with increasing both the chain length of n-alkanes and their content, the reflection intensity of the asphalt binder decreased, and the refractive index and extinction coefficient increased accordingly. On the whole, ellipsometry-based optical testing is a promising method for rapid and non-destructive identification of wax in asphalt.
Spectroscopic ellipsometry studies on optical constants of crystalline wax-doped asphalt binders
Asphalt pavement possesses the characteristics of strong sunlight absorption, which lead to the aging of asphalt binder. Asphalt aging is one of the leading causes of the performance deterioration in the asphalt pavement, and the appearance of crystalline wax (paraffin wax) during aging has a significant effect on optical properties (absorption and reflection) of the asphalt binder. In this paper, effects of the crystalline wax on optical properties of the asphalt binder were investigated using the spectroscopic ellipsometry (SE) technique, and a new method for the quantification of the crystalline wax in asphalt was also developed. Cold Lake asphalt doped with different contents of n-alkanes (eicosane, triacontane, and tetracontane) were tested by the SE. The results showed that there is a close linear relationship between the optical constants and wax content of the asphalt binder. In addition, with increasing both the chain length of n-alkanes and their content, the reflection intensity of the asphalt binder decreased, and the refractive index and extinction coefficient increased accordingly. On the whole, ellipsometry-based optical testing is a promising method for rapid and non-destructive identification of wax in asphalt.
Spectroscopic ellipsometry studies on optical constants of crystalline wax-doped asphalt binders
Zhang, Haopeng (Autor:in) / Xie, Qingshan (Autor:in) / Ding, Haibo (Autor:in) / Rahman, Ali (Autor:in)
28.01.2023
Aufsatz (Zeitschrift)
Elektronische Ressource
Englisch
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