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Environmentally Friendly Recovery of Li2CO3 from Spent Lithium-Ion Batteries by Oxidation and Selective Leaching Process
https://orcid.org/0000-0002-7562-7903
https://orcid.org/0000-0002-9598-9979
https://orcid.org/0000-0001-6795-371X
https://orcid.org/0000-0001-9984-6636
https://orcid.org/0000-0002-6968-8080
https://orcid.org/0000-0002-1553-5679
The extraction of valuable metals from spent Ni–Co–Mn oxide (NCM) cathodes typically encounters the use of strong acids or alkalis, often leading to secondary pollution. Herein, an environmentally friendly recovery route for the selective extraction of lithium (Li) by using sodium persulfate (Na2S2O8) as the sole leaching agent was proposed. Under the optimized conditions, the leaching efficiency of Li achieved 98.02%, and the selective leaching efficiency of Li was 94.80%. Moreover, the lithium carbonate (Li2CO3) product was recovered from the Li-rich filtrate with a high purity of 99.5%. The mechanism of Li selective leaching was revealed by means of wet chemistry, kinetics, thermodynamics, and solid-phase analysis. During selective leaching, free radicals SO4 •– and •OH, hydron ion (H+), and sodium ion (Na+) were generated by Na2S2O8. These free radicals can increase the redox potential of the leaching system. Under these conditions, Co and Mn elements were both maintained in a high valence state and the cathode structure was collapsed, thus contributing to the leaching of Li. The proposed environmentally friendly recovery process of Li from spent NCM cathodes is promising for practical applications, offering significant economic benefits.
Environmentally Friendly Recovery of Li2CO3 from Spent Lithium-Ion Batteries by Oxidation and Selective Leaching Process
https://orcid.org/0000-0002-7562-7903
https://orcid.org/0000-0002-9598-9979
https://orcid.org/0000-0001-6795-371X
https://orcid.org/0000-0001-9984-6636
https://orcid.org/0000-0002-6968-8080
https://orcid.org/0000-0002-1553-5679
The extraction of valuable metals from spent Ni–Co–Mn oxide (NCM) cathodes typically encounters the use of strong acids or alkalis, often leading to secondary pollution. Herein, an environmentally friendly recovery route for the selective extraction of lithium (Li) by using sodium persulfate (Na2S2O8) as the sole leaching agent was proposed. Under the optimized conditions, the leaching efficiency of Li achieved 98.02%, and the selective leaching efficiency of Li was 94.80%. Moreover, the lithium carbonate (Li2CO3) product was recovered from the Li-rich filtrate with a high purity of 99.5%. The mechanism of Li selective leaching was revealed by means of wet chemistry, kinetics, thermodynamics, and solid-phase analysis. During selective leaching, free radicals SO4 •– and •OH, hydron ion (H+), and sodium ion (Na+) were generated by Na2S2O8. These free radicals can increase the redox potential of the leaching system. Under these conditions, Co and Mn elements were both maintained in a high valence state and the cathode structure was collapsed, thus contributing to the leaching of Li. The proposed environmentally friendly recovery process of Li from spent NCM cathodes is promising for practical applications, offering significant economic benefits.
Environmentally Friendly Recovery of Li2CO3 from Spent Lithium-Ion Batteries by Oxidation and Selective Leaching Process
https://orcid.org/0000-0002-7562-7903
https://orcid.org/0000-0002-9598-9979
https://orcid.org/0000-0001-6795-371X
https://orcid.org/0000-0001-9984-6636
https://orcid.org/0000-0002-6968-8080
https://orcid.org/0000-0002-1553-5679
The extraction of valuable metals from spent Ni–Co–Mn oxide (NCM) cathodes typically encounters the use of strong acids or alkalis, often leading to secondary pollution. Herein, an environmentally friendly recovery route for the selective extraction of lithium (Li) by using sodium persulfate (Na2S2O8) as the sole leaching agent was proposed. Under the optimized conditions, the leaching efficiency of Li achieved 98.02%, and the selective leaching efficiency of Li was 94.80%. Moreover, the lithium carbonate (Li2CO3) product was recovered from the Li-rich filtrate with a high purity of 99.5%. The mechanism of Li selective leaching was revealed by means of wet chemistry, kinetics, thermodynamics, and solid-phase analysis. During selective leaching, free radicals SO4 •– and •OH, hydron ion (H+), and sodium ion (Na+) were generated by Na2S2O8. These free radicals can increase the redox potential of the leaching system. Under these conditions, Co and Mn elements were both maintained in a high valence state and the cathode structure was collapsed, thus contributing to the leaching of Li. The proposed environmentally friendly recovery process of Li from spent NCM cathodes is promising for practical applications, offering significant economic benefits.
Environmentally Friendly Recovery of Li2CO3 from Spent Lithium-Ion Batteries by Oxidation and Selective Leaching Process
Zheng, Ying (author) / Yang, Zhe (author) / Li, Zhaoyang (author) / Hu, Guang (author) / Liang, Sha (author) / Yu, Wenbo (author) / Yuan, Shushan (author) / Duan, Huabo (author) / Huang, Liang (author) / Hu, Jingping (author)
ACS ES&T Engineering ; 4 ; 1927-1936
2024-08-09
Article (Journal)
Electronic Resource
English
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