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Codimerization of ethylene with isoprene

Seidov, N.M. / Geydarov, M.A. / Kengerli, R.A. / Maksimova, M.V.

Abstract 1. 1. During the codimerization of ethylene with isoprene in the presence of iron acetyl acetonate and tri-isobutyl aluminium. 3-methyl-1,4-hexadiene is chiefly formed which under process conditions is partially isomerized to 3-methyl-1, 3-hexadiene. 2. 2. Process kinetics were studied and the rate, order and activation energy of codimerization of ethylene with isoprene and isomerization of 3-methyl-1, 4-hexadiene to 3-methyl-1,3-hexadiene, calculated.

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Codimerization of ethylene with isoprene

Seidov, N.M. / Geydarov, M.A. / Kengerli, R.A. / Maksimova, M.V.

Abstract 1. 1. During the codimerization of ethylene with isoprene in the presence of iron acetyl acetonate and tri-isobutyl aluminium. 3-methyl-1,4-hexadiene is chiefly formed which under process conditions is partially isomerized to 3-methyl-1, 3-hexadiene. 2. 2. Process kinetics were studied and the rate, order and activation energy of codimerization of ethylene with isoprene and isomerization of 3-methyl-1, 4-hexadiene to 3-methyl-1,3-hexadiene, calculated.

Codimerization of ethylene with isoprene

Seidov, N.M. / Geydarov, M.A. / Kengerli, R.A. / Maksimova, M.V.

Abstract 1. 1. During the codimerization of ethylene with isoprene in the presence of iron acetyl acetonate and tri-isobutyl aluminium. 3-methyl-1,4-hexadiene is chiefly formed which under process conditions is partially isomerized to 3-methyl-1, 3-hexadiene. 2. 2. Process kinetics were studied and the rate, order and activation energy of codimerization of ethylene with isoprene and isomerization of 3-methyl-1, 4-hexadiene to 3-methyl-1,3-hexadiene, calculated.

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Title:

Codimerization of ethylene with isoprene

Contributors:

Seidov, N.M. (author) / Geydarov, M.A. (author) / Kengerli, R.A. (author) / Maksimova, M.V. (author)

Published in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 13 ; 11-18

Publication date:

1971-07-05

Size:

8 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(73)90024-5

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

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