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Codimerization of ethylene with n-pentenes and propylene with n-butenes on an alkaline catalyst

Ansheles, V.R. / Pis'man, I.I. / Tarayan, K.L. / Portyanskii, A.Ye. / Makarov, V.M.

Abstract 1. 1. 3-Ethylpent-1-ene is the main product of codimerization of ethylene with n-pentenes on a Na/K2CO3 catalyst independent of the position of the multiple bond in the initial olefin. 2. 2. 3,4-Dimethylpent-1-ene is the main component in products of codimerization of n-butylenes with propylene; 4-methylhex-1-ene and 5-methylhex-2-ene are formed in small amounts even when butylene-2 is used as raw material.

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Codimerization of ethylene with n-pentenes and propylene with n-butenes on an alkaline catalyst

Ansheles, V.R. / Pis'man, I.I. / Tarayan, K.L. / Portyanskii, A.Ye. / Makarov, V.M.

Abstract 1. 1. 3-Ethylpent-1-ene is the main product of codimerization of ethylene with n-pentenes on a Na/K2CO3 catalyst independent of the position of the multiple bond in the initial olefin. 2. 2. 3,4-Dimethylpent-1-ene is the main component in products of codimerization of n-butylenes with propylene; 4-methylhex-1-ene and 5-methylhex-2-ene are formed in small amounts even when butylene-2 is used as raw material.

Codimerization of ethylene with n-pentenes and propylene with n-butenes on an alkaline catalyst

Ansheles, V.R. / Pis'man, I.I. / Tarayan, K.L. / Portyanskii, A.Ye. / Makarov, V.M.

Abstract 1. 1. 3-Ethylpent-1-ene is the main product of codimerization of ethylene with n-pentenes on a Na/K2CO3 catalyst independent of the position of the multiple bond in the initial olefin. 2. 2. 3,4-Dimethylpent-1-ene is the main component in products of codimerization of n-butylenes with propylene; 4-methylhex-1-ene and 5-methylhex-2-ene are formed in small amounts even when butylene-2 is used as raw material.

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Title:

Codimerization of ethylene with n-pentenes and propylene with n-butenes on an alkaline catalyst

Contributors:

Ansheles, V.R. (author) / Pis'man, I.I. (author) / Tarayan, K.L. (author) / Portyanskii, A.Ye. (author) / Makarov, V.M. (author)

Published in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 16 ; 12-19

Publication date:

1975-03-11

Size:

8 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(76)90045-9

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

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