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Dehydrocyclization of olefins and alkadienes in the presence of alumina-palladium catalysts

Fadeyev, V.S. / Gostunskaya, I.V. / Kazanskii, B.A.

Abstract 1. 1. A study was made of aromatization of hex-1-ene, hexa-1,5-diene, hexa-2,4-diene, methylcyclopentane and 1-methylcyclopent-2-ene. 2. 2. The degree of aromatization of olefins increases with an increase in the unsaturation of initial hydrocarbons. 3. 3. The degree of aromatization of hexene and hexadiene in helium is higher than in hydrogen. The degree of C5-dehydrocyclization of olefins, on the other hand, is higher in hydrogen than in helium.

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Dehydrocyclization of olefins and alkadienes in the presence of alumina-palladium catalysts

Fadeyev, V.S. / Gostunskaya, I.V. / Kazanskii, B.A.

Abstract 1. 1. A study was made of aromatization of hex-1-ene, hexa-1,5-diene, hexa-2,4-diene, methylcyclopentane and 1-methylcyclopent-2-ene. 2. 2. The degree of aromatization of olefins increases with an increase in the unsaturation of initial hydrocarbons. 3. 3. The degree of aromatization of hexene and hexadiene in helium is higher than in hydrogen. The degree of C5-dehydrocyclization of olefins, on the other hand, is higher in hydrogen than in helium.

Dehydrocyclization of olefins and alkadienes in the presence of alumina-palladium catalysts

Fadeyev, V.S. / Gostunskaya, I.V. / Kazanskii, B.A.

Abstract 1. 1. A study was made of aromatization of hex-1-ene, hexa-1,5-diene, hexa-2,4-diene, methylcyclopentane and 1-methylcyclopent-2-ene. 2. 2. The degree of aromatization of olefins increases with an increase in the unsaturation of initial hydrocarbons. 3. 3. The degree of aromatization of hexene and hexadiene in helium is higher than in hydrogen. The degree of C5-dehydrocyclization of olefins, on the other hand, is higher in hydrogen than in helium.

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Title:

Dehydrocyclization of olefins and alkadienes in the presence of alumina-palladium catalysts

Contributors:

Fadeyev, V.S. (author) / Gostunskaya, I.V. (author) / Kazanskii, B.A. (author)

Published in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 11 ; 135-142

Publication date:

1970-07-24

Size:

8 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(71)90019-0

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

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