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Mechanism of liquid-phase oxidation of 2-methylpent-2-ene

Parfenov, V.M. / Maizus, Z.K.

Abstract 1. 1. The main products of oxidation of 2-methylpent-2-ene oxide, polymeric peroxide and equimolecular quantities of acetic and formic acids and acetone. 2. 2. The rate of oxide formation is much higher than the rate of accumulation of products from the conversion of acyl and alkyl peroxide radicals. A hypothesis is put forward concerning a new process and mechanism of epoxidation of olefins.

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Mechanism of liquid-phase oxidation of 2-methylpent-2-ene

Parfenov, V.M. / Maizus, Z.K.

Abstract 1. 1. The main products of oxidation of 2-methylpent-2-ene oxide, polymeric peroxide and equimolecular quantities of acetic and formic acids and acetone. 2. 2. The rate of oxide formation is much higher than the rate of accumulation of products from the conversion of acyl and alkyl peroxide radicals. A hypothesis is put forward concerning a new process and mechanism of epoxidation of olefins.

Mechanism of liquid-phase oxidation of 2-methylpent-2-ene

Parfenov, V.M. / Maizus, Z.K.

Abstract 1. 1. The main products of oxidation of 2-methylpent-2-ene oxide, polymeric peroxide and equimolecular quantities of acetic and formic acids and acetone. 2. 2. The rate of oxide formation is much higher than the rate of accumulation of products from the conversion of acyl and alkyl peroxide radicals. A hypothesis is put forward concerning a new process and mechanism of epoxidation of olefins.

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Title:

Mechanism of liquid-phase oxidation of 2-methylpent-2-ene

Contributors:

Parfenov, V.M. (author) / Maizus, Z.K. (author)

Published in:

Petroleum Chemistry: USSR (English Translation of Neftekhimiya) ; 11 ; 109-115

Publication date:

1970-06-15

Size:

7 pages

ISSN:

DOI:

https://doi.org/10.1016/0031-6458(71)90047-5

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

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