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Composite hydrogel material with self-adaptive solar response as well as preparation method and application of composite hydrogel material
The invention provides a composite hydrogel material self-adaptive to solar response and a preparation method and application thereof.The composite hydrogel material comprises a photo-thermal material and a thermal response phase change material, and the photo-thermal material is a nano composite material formed by compounding a metal-based nano material with a two-dimensional layered nano material; the thermal response phase change material is hydrogel formed by copolymerizing a thermochromic material and a high polymer material containing hydroxyl and carboxyl; the high polymer material containing hydroxyl and carboxyl can provide hydrogen bonds, so that the heat storage capacity is improved, and meanwhile, the solar energy modulation capability of the composite hydrogel is favorably improved. According to the invention, a small amount of nano composite material is used as a light capture nano heater to generate a synergistically enhanced photothermal effect and stimulate the thermal response of the hydrogel; when the composite hydrogel material is applied to an intelligent window or a wearable material, the composite hydrogel material has excellent light absorption performance, photothermal conversion performance and high solar energy modulation amplitude, has a temperature adjusting effect in the aspect of self-adaptive solar energy modulation, and has important significance in energy conservation.
本发明提供了一种自适应太阳能响应的复合水凝胶材料及其制备方法与应用,复合水凝胶材料包括光热材料与热响应相变材料,光热材料为金属基纳米材料复合二维层状纳米材料形成的纳米复合材料,热响应相变材料是由热致变色材料与含羟基和羧基的高分子材料共聚而成的水凝胶;含羟基和羧基的高分子材料可提供氢键,提高储热容量,同时有助于提高复合水凝胶的太阳能调制能力。本发明利用少量的纳米复合材料作为光捕获纳米加热器,产生协同增强的光热效应,刺激水凝胶的热响应;该复合水凝胶材料应用于智能窗户或可穿戴材料时,具有优异的光吸收性能、光热转换性能以及高的太阳能调制幅度,在自适应太阳能调制方面具有调温的效果,对于节能具有重要意义。
Composite hydrogel material with self-adaptive solar response as well as preparation method and application of composite hydrogel material
The invention provides a composite hydrogel material self-adaptive to solar response and a preparation method and application thereof.The composite hydrogel material comprises a photo-thermal material and a thermal response phase change material, and the photo-thermal material is a nano composite material formed by compounding a metal-based nano material with a two-dimensional layered nano material; the thermal response phase change material is hydrogel formed by copolymerizing a thermochromic material and a high polymer material containing hydroxyl and carboxyl; the high polymer material containing hydroxyl and carboxyl can provide hydrogen bonds, so that the heat storage capacity is improved, and meanwhile, the solar energy modulation capability of the composite hydrogel is favorably improved. According to the invention, a small amount of nano composite material is used as a light capture nano heater to generate a synergistically enhanced photothermal effect and stimulate the thermal response of the hydrogel; when the composite hydrogel material is applied to an intelligent window or a wearable material, the composite hydrogel material has excellent light absorption performance, photothermal conversion performance and high solar energy modulation amplitude, has a temperature adjusting effect in the aspect of self-adaptive solar energy modulation, and has important significance in energy conservation.
本发明提供了一种自适应太阳能响应的复合水凝胶材料及其制备方法与应用,复合水凝胶材料包括光热材料与热响应相变材料,光热材料为金属基纳米材料复合二维层状纳米材料形成的纳米复合材料,热响应相变材料是由热致变色材料与含羟基和羧基的高分子材料共聚而成的水凝胶;含羟基和羧基的高分子材料可提供氢键,提高储热容量,同时有助于提高复合水凝胶的太阳能调制能力。本发明利用少量的纳米复合材料作为光捕获纳米加热器,产生协同增强的光热效应,刺激水凝胶的热响应;该复合水凝胶材料应用于智能窗户或可穿戴材料时,具有优异的光吸收性能、光热转换性能以及高的太阳能调制幅度,在自适应太阳能调制方面具有调温的效果,对于节能具有重要意义。
Composite hydrogel material with self-adaptive solar response as well as preparation method and application of composite hydrogel material
自适应太阳能响应的复合水凝胶材料及其制备方法与应用
LI YINGYING (author) / WANG DONG (author) / WANG YANQIU (author) / WANG WENWEN (author)
2023-05-02
Patent
Electronic Resource
Chinese
IPC:
C08L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
,
Massen auf Basis makromolekularer Verbindungen
/
C08F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
,
Makromolekulare Verbindungen, erhalten durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind
/
C08J
Verarbeitung
,
WORKING-UP
/
C08K
Verwendung von anorganischen oder nichtmakromolekularen organischen Stoffen als Zusatzstoffe
,
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
/
E06B
Feste oder bewegliche Abschlüsse für Öffnungen in Bauwerken, Fahrzeugen, Zäunen oder ähnlichen Einfriedungen allgemein, z.B. Türen, Fenster, Läden, Tore
,
FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES, OR LIKE ENCLOSURES, IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
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