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Surface-modified tetradecane phase change microcapsule, temperature-control anti-freezing concrete and preparation method of surface-modified tetradecane phase change microcapsule
According to the surface modified tetradecane phase change microcapsule, the surface modified tetradecane phase change microcapsule is a nano SiO2 surface modified tetradecane phase change microcapsule, a phase change material is tetradecane, and a supporting material (poly (n-butyl methacrylate)) is used as a packaging shell of the phase change microcapsule. The invention relates to temperature-control anti-freezing concrete. Nano SiO2 surface modified tetradecane phase change microcapsules are used as a temperature-control heat storage material. According to the nano SiO2 surface modified tetradecane phase change microcapsule prepared by the preparation method disclosed by the invention, the interface performance of the microcapsule and a cement-based material is modified and improved by utilizing a nucleation effect and a pozzolanic effect of SiO2 in a hydration process of the cement-based material; the temperature-control anti-freezing concrete material based on phase change heat storage has good mechanical performance and excellent anti-freezing and thawing performance, and can effectively improve the durability of supporting structure concrete in the construction and use process of tunnels in cold regions.
一种表面改性十四烷相变微胶囊,所述表面改性十四烷相变微胶囊为纳米SiO2表面改性十四烷相变微胶囊,相变材料为十四烷,支撑材料聚甲基丙烯酸正丁酯作为相变微胶囊的封装外壳。一种控温抗冻混凝土,采用纳米SiO2表面改性十四烷相变微胶囊作为控温储热材料。本发明制得的纳米SiO2表面改性十四烷相变微胶囊利用SiO2在水泥基材料水化过程中的成核效应以及火山灰效应,对微胶囊与水泥基材料界面性能进行改性及提升,所述基于相变储热的控温抗冻混凝土材料在具有良好的机械性能的同时还具有优异的抗冻融性能,其在寒区隧道建设及使用过程中可以有效的改善支护结构混凝土的耐久性。
Surface-modified tetradecane phase change microcapsule, temperature-control anti-freezing concrete and preparation method of surface-modified tetradecane phase change microcapsule
According to the surface modified tetradecane phase change microcapsule, the surface modified tetradecane phase change microcapsule is a nano SiO2 surface modified tetradecane phase change microcapsule, a phase change material is tetradecane, and a supporting material (poly (n-butyl methacrylate)) is used as a packaging shell of the phase change microcapsule. The invention relates to temperature-control anti-freezing concrete. Nano SiO2 surface modified tetradecane phase change microcapsules are used as a temperature-control heat storage material. According to the nano SiO2 surface modified tetradecane phase change microcapsule prepared by the preparation method disclosed by the invention, the interface performance of the microcapsule and a cement-based material is modified and improved by utilizing a nucleation effect and a pozzolanic effect of SiO2 in a hydration process of the cement-based material; the temperature-control anti-freezing concrete material based on phase change heat storage has good mechanical performance and excellent anti-freezing and thawing performance, and can effectively improve the durability of supporting structure concrete in the construction and use process of tunnels in cold regions.
一种表面改性十四烷相变微胶囊,所述表面改性十四烷相变微胶囊为纳米SiO2表面改性十四烷相变微胶囊,相变材料为十四烷,支撑材料聚甲基丙烯酸正丁酯作为相变微胶囊的封装外壳。一种控温抗冻混凝土,采用纳米SiO2表面改性十四烷相变微胶囊作为控温储热材料。本发明制得的纳米SiO2表面改性十四烷相变微胶囊利用SiO2在水泥基材料水化过程中的成核效应以及火山灰效应,对微胶囊与水泥基材料界面性能进行改性及提升,所述基于相变储热的控温抗冻混凝土材料在具有良好的机械性能的同时还具有优异的抗冻融性能,其在寒区隧道建设及使用过程中可以有效的改善支护结构混凝土的耐久性。
Surface-modified tetradecane phase change microcapsule, temperature-control anti-freezing concrete and preparation method of surface-modified tetradecane phase change microcapsule
表面改性十四烷相变微胶囊、控温抗冻混凝土及制备方法
CHOI SUNG-AE (author) / XIA WEI (author) / XU XUEFENG (author) / ZENG GUANG (author) / LI GUHUA (author) / LIU PIN (author)
2023-12-05
Patent
Electronic Resource
Chinese
IPC:
C04B
Kalk
,
LIME
/
C08F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
,
Makromolekulare Verbindungen, erhalten durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind
/
C09K
Materialien für Anwendungen, soweit nicht anderweitig vorgesehen
,
MATERIALS FOR APPLICATIONS NOT OTHERWISE PROVIDED FOR
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