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High-thermal-expansion-coefficient high-strength low-temperature co-fired ceramic composite material as well as preparation method and application thereof
The invention relates to the technical field of ceramic materials, in particular to a high-thermal-expansion-coefficient high-strength low-temperature co-fired ceramic composite material and a preparation method and application thereof. The invention discloses a low-temperature co-fired ceramic composite material with a high thermal expansion coefficient and high strength. The low-temperature co-fired ceramic composite material contains a CaMgSi2O6 crystal phase, a BaAl2Si2O8 crystal phase and a cristobalite crystal phase, the thermal expansion coefficient of the ceramic composite material is greater than 10ppm/DEG C, and the dielectric loss is less than 0.001. According to the ceramic composite material disclosed by the invention, CaMgSi2O6 is generated by sintering and crystallizing the calcium aluminum magnesium barium titanium silicon glass, and the calcium aluminum magnesium barium titanium silicon glass has a relatively high thermal expansion coefficient; by adding SiO2, a cristobalite phase can be separated out, and the thermal expansion coefficient of the material is further increased while the dielectric constant of the material is reduced; by adding Al2O3, generation of a BaAl2Si2O8 phase is facilitated, the dielectric loss of the material is reduced, and the bending strength of the material is improved.
本发明涉及陶瓷材料的技术领域,具体涉及一种高热膨胀系数高强度低温共烧陶瓷复合材料及其制备方法和应用。本申请公开了一种高热膨胀系数高强度低温共烧陶瓷复合材料,含有CaMgSi2O6晶相、BaAl2Si2O8晶相、方石英晶相;所述陶瓷复合材料的热膨胀系数>10ppm/℃、介电损耗<0.001。本申请所述的陶瓷复合材料,通过钙铝镁钡钛硅玻璃烧结析晶,生成CaMgSi2O6,且钙铝镁钡钛硅玻璃本身具有比较高的热膨胀系数;添加SiO2中有助于析出方石英相,降低材料的介电常数的同时进一步增加材料热膨胀系数;添加Al2O3有利于生成BaAl2Si2O8相,降低材料的介电损耗和提高材料抗弯强度。
High-thermal-expansion-coefficient high-strength low-temperature co-fired ceramic composite material as well as preparation method and application thereof
The invention relates to the technical field of ceramic materials, in particular to a high-thermal-expansion-coefficient high-strength low-temperature co-fired ceramic composite material and a preparation method and application thereof. The invention discloses a low-temperature co-fired ceramic composite material with a high thermal expansion coefficient and high strength. The low-temperature co-fired ceramic composite material contains a CaMgSi2O6 crystal phase, a BaAl2Si2O8 crystal phase and a cristobalite crystal phase, the thermal expansion coefficient of the ceramic composite material is greater than 10ppm/DEG C, and the dielectric loss is less than 0.001. According to the ceramic composite material disclosed by the invention, CaMgSi2O6 is generated by sintering and crystallizing the calcium aluminum magnesium barium titanium silicon glass, and the calcium aluminum magnesium barium titanium silicon glass has a relatively high thermal expansion coefficient; by adding SiO2, a cristobalite phase can be separated out, and the thermal expansion coefficient of the material is further increased while the dielectric constant of the material is reduced; by adding Al2O3, generation of a BaAl2Si2O8 phase is facilitated, the dielectric loss of the material is reduced, and the bending strength of the material is improved.
本发明涉及陶瓷材料的技术领域,具体涉及一种高热膨胀系数高强度低温共烧陶瓷复合材料及其制备方法和应用。本申请公开了一种高热膨胀系数高强度低温共烧陶瓷复合材料,含有CaMgSi2O6晶相、BaAl2Si2O8晶相、方石英晶相;所述陶瓷复合材料的热膨胀系数>10ppm/℃、介电损耗<0.001。本申请所述的陶瓷复合材料,通过钙铝镁钡钛硅玻璃烧结析晶,生成CaMgSi2O6,且钙铝镁钡钛硅玻璃本身具有比较高的热膨胀系数;添加SiO2中有助于析出方石英相,降低材料的介电常数的同时进一步增加材料热膨胀系数;添加Al2O3有利于生成BaAl2Si2O8相,降低材料的介电损耗和提高材料抗弯强度。
High-thermal-expansion-coefficient high-strength low-temperature co-fired ceramic composite material as well as preparation method and application thereof
一种高热膨胀系数高强度低温共烧陶瓷复合材料及其制备方法和应用
HE SENLIN (author) / GUO HAI (author) / GONG XINGYI (author)
2024-05-14
Patent
Electronic Resource
Chinese
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