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Sodium hypochlorite stabilization of waste incineration fly ash
The invention relates to the field of fly ash treatment, in particular to a sodium hypochlorite stabilized waste incineration fly ash which comprises a raw material manufacturing module, a hydro-thermal treatment module and a brick making module, the raw material manufacturing module comprises manufacturing equipment cleaning, raw material mixing and raw material processing and manufacturing, and the raw materials are processed and manufactured through detection of an X-ray diffractometer. It is found that original fly ash contains chlorine and sulfite ions, and the chlorine and sulfite ions exist in the forms of NaCl, KCl and (CaSO3) 2. H2O respectively. No obvious characteristic peaks of NaCl, KCl and (CaSO3) 2. H2O are found in the sample, which indicates that the removal of chlorine element and the oxidation of sulfite radical can be realized by the direct hydrothermal method (one-step method) of sodium hypochlorite ball milling and washing and the hydrothermal method (two-step method) of sodium hypochlorite after the sodium hypochlorite ball milling, washing and drying, and the XRD result confirms that after the sodium hypochlorite ball milling, washing and drying, the removal of the chlorine element and the oxidation of sulfite radical can be realized by the direct hydrothermal method (one-step method) of sodium hypochlorite ball milling, washing and drying. And then sodium hypochlorite is added for hydrothermal treatment, so that the removal of chlorine element and the oxidation of sulfite can be realized, and good dechlorination and sulfur stabilization effects are achieved.
本发明涉及飞灰处理领域，具体的说是次氯酸钠稳定垃圾焚烧飞灰，包括原料制作模块和水热处理模块以及制砖模块，所述原料制作模块包括制作设备清洗和原料混合以及原料加工制作，通过X射线衍射仪的检测，发现原始飞灰含有氯元素以及亚硫酸根离子，他们分别以NaCl、KCl和(CaSO3)2·H2O形式存在。样品中均未发现明显的NaCl和KCl以及(CaSO3)2·H2O的特征峰，这就说明次氯酸钠球磨水洗直接水热(一步法)、次氯酸钠球磨水洗干燥后，再加次氯酸钠水热(两步法)都能够实现氯元素的脱除及亚硫酸根的氧化，通过XRD的结果确认，说明次氯酸钠球磨水洗干燥后，再加次氯酸钠水热能够实现氯元素的脱除及亚硫酸根的氧化，具有很好的脱氯和稳定硫的效果。
Sodium hypochlorite stabilization of waste incineration fly ash
The invention relates to the field of fly ash treatment, in particular to a sodium hypochlorite stabilized waste incineration fly ash which comprises a raw material manufacturing module, a hydro-thermal treatment module and a brick making module, the raw material manufacturing module comprises manufacturing equipment cleaning, raw material mixing and raw material processing and manufacturing, and the raw materials are processed and manufactured through detection of an X-ray diffractometer. It is found that original fly ash contains chlorine and sulfite ions, and the chlorine and sulfite ions exist in the forms of NaCl, KCl and (CaSO3) 2. H2O respectively. No obvious characteristic peaks of NaCl, KCl and (CaSO3) 2. H2O are found in the sample, which indicates that the removal of chlorine element and the oxidation of sulfite radical can be realized by the direct hydrothermal method (one-step method) of sodium hypochlorite ball milling and washing and the hydrothermal method (two-step method) of sodium hypochlorite after the sodium hypochlorite ball milling, washing and drying, and the XRD result confirms that after the sodium hypochlorite ball milling, washing and drying, the removal of the chlorine element and the oxidation of sulfite radical can be realized by the direct hydrothermal method (one-step method) of sodium hypochlorite ball milling, washing and drying. And then sodium hypochlorite is added for hydrothermal treatment, so that the removal of chlorine element and the oxidation of sulfite can be realized, and good dechlorination and sulfur stabilization effects are achieved.
本发明涉及飞灰处理领域，具体的说是次氯酸钠稳定垃圾焚烧飞灰，包括原料制作模块和水热处理模块以及制砖模块，所述原料制作模块包括制作设备清洗和原料混合以及原料加工制作，通过X射线衍射仪的检测，发现原始飞灰含有氯元素以及亚硫酸根离子，他们分别以NaCl、KCl和(CaSO3)2·H2O形式存在。样品中均未发现明显的NaCl和KCl以及(CaSO3)2·H2O的特征峰，这就说明次氯酸钠球磨水洗直接水热(一步法)、次氯酸钠球磨水洗干燥后，再加次氯酸钠水热(两步法)都能够实现氯元素的脱除及亚硫酸根的氧化，通过XRD的结果确认，说明次氯酸钠球磨水洗干燥后，再加次氯酸钠水热能够实现氯元素的脱除及亚硫酸根的氧化，具有很好的脱氯和稳定硫的效果。
Sodium hypochlorite stabilization of waste incineration fly ash
次氯酸钠稳定垃圾焚烧飞灰
ZHOU ZHENGYUAN (author) / XIA GUANGHUA (author) / WU WENXIN (author) / LIAO RUNHUA (author) / ZHANG YING (author)
2024-07-05
Patent
Electronic Resource
Chinese
Stabilization treatment method for waste incineration fly ash
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