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MACROPOROUS TITANIUM COMPOUND MONOLITH AND METHOD FOR MANUFACTURING SAME
Provided are a macroporous titanium compound monolith and a production method thereof, the macroporous titanium compound monolith having a framework that is composed of a titanium compound other than titanium dioxide, having controlled macropores, and having electron conductivity, the titanium compound being oxygen-deficient titanium oxide, titanium oxynitride, or titanium nitride. Provided is a method including: placing a macroporous titanium dioxide monolith and a metal having titanium-reducing ability in a container, the macroporous titanium dioxide monolith having a co-continuous structure of a macropore and a framework that is composed of titanium dioxide; creating a vacuum atmosphere or an inert gas atmosphere within the container; and heating the monolith and the metal to cause gas-phase reduction that removes oxygen atom from the titanium dioxide composing the monolith by the metal acting as an oxygen getter, thereby obtaining a macroporous oxygen-deficient titanium oxide monolith having a co-continuous structure of the macropore and a framework that is composed of oxygen-deficient titanium oxide, the macroporous oxygen-deficient titanium oxide monolith having electron conductivity derived from the oxygen-deficient titanium oxide.
MACROPOROUS TITANIUM COMPOUND MONOLITH AND METHOD FOR MANUFACTURING SAME
Provided are a macroporous titanium compound monolith and a production method thereof, the macroporous titanium compound monolith having a framework that is composed of a titanium compound other than titanium dioxide, having controlled macropores, and having electron conductivity, the titanium compound being oxygen-deficient titanium oxide, titanium oxynitride, or titanium nitride. Provided is a method including: placing a macroporous titanium dioxide monolith and a metal having titanium-reducing ability in a container, the macroporous titanium dioxide monolith having a co-continuous structure of a macropore and a framework that is composed of titanium dioxide; creating a vacuum atmosphere or an inert gas atmosphere within the container; and heating the monolith and the metal to cause gas-phase reduction that removes oxygen atom from the titanium dioxide composing the monolith by the metal acting as an oxygen getter, thereby obtaining a macroporous oxygen-deficient titanium oxide monolith having a co-continuous structure of the macropore and a framework that is composed of oxygen-deficient titanium oxide, the macroporous oxygen-deficient titanium oxide monolith having electron conductivity derived from the oxygen-deficient titanium oxide.
MACROPOROUS TITANIUM COMPOUND MONOLITH AND METHOD FOR MANUFACTURING SAME
MONOLITH AUS EINER MAKROPORÖSEN TITANVERBINDUNG UND VERFAHREN ZUR HERSTELLUNG DAVON
MONOLITHE COMPOSITE DE TITANE MACROPOREUX ET SON PROCÉDÉ DE FABRICATION
KAGEYAMA HIROSHI (author) / NAKANISHI KAZUKI (author) / KOBAYASHI YOJI (author) / KITADA ATSUSHI (author) / HASEGAWA GEORGE (author)
2021-12-15
Patent
Electronic Resource
English
Macroporous titanium compound monolith and method for producing same
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