Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer: Fid-Bau Portal

Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer

Maksimov, A. L. / Kulikov, A. B. / Pugacheva, A. A. / Vilesov, A. S. / Smirnov, M. B. / Galkina, E. V. / Reshetnikov, D. M. / Zvinchuk, A. A.

Abstract

Abstract The oligomerization of higher α-olefins over a set of heterogeneous mesoporous catalysts has been studied using the example of decene-1. It has been shown that mesoporous catalysts based on the sulfonated, perfluorinated copolymer F-4SF exhibit high activity in oligomerization of decene-1 in both a batch reactor and a flow system: in the former case, the olefin conversion reaches 95–99% with the yield of dimers of 90–95%; in the latter case, the conversion of decene-1 to oligomers exceeds 70%.

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Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer

Maksimov, A. L. / Kulikov, A. B. / Pugacheva, A. A. / Vilesov, A. S. / Smirnov, M. B. / Galkina, E. V. / Reshetnikov, D. M. / Zvinchuk, A. A.

Abstract

Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer

Maksimov, A. L. / Kulikov, A. B. / Pugacheva, A. A. / Vilesov, A. S. / Smirnov, M. B. / Galkina, E. V. / Reshetnikov, D. M. / Zvinchuk, A. A.

Abstract

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Title:

Oligomerization of higher α-olefins over catalysts containing an F-4SF perfluorinated copolymer

Contributors:

Maksimov, A. L. (author) / Kulikov, A. B. (author) / Pugacheva, A. A. (author) / Vilesov, A. S. (author) / Smirnov, M. B. (author) / Galkina, E. V. (author) / Reshetnikov, D. M. (author) / Zvinchuk, A. A. (author)

Published in:

Petroleum Chemistry ; 54 ; 120-127

Publication date:

2014-03-01

Size:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544114020066

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

oligomerization , decene-1 , mesoporous catalysts , perfluorinated copolymer Chemistry , Industrial Chemistry/Chemical Engineering

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