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Modified mesoporous catalysts based on Al-HMS and Al-MCF for the oligomerization of α-olefins

Kulikov, A. B. / Pugacheva, A. A. / Maksimov, A. L.

Abstract High-performance decene-1 oligomerization catalysts based on mesoporous Al-HMS and Al-MCF aluminosilicates modified with an F-4SF sulfonated perfluorinated copolymer have been synthesized. Under batch conditions with a conversion of 90% and in a flow system with a conversion of 83%, these catalysts provide the formation of an oligomerization product with viscosity properties characteristic of poly-α-olefins, the precursors of poly-α-olefin oils.

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Modified mesoporous catalysts based on Al-HMS and Al-MCF for the oligomerization of α-olefins

Kulikov, A. B. / Pugacheva, A. A. / Maksimov, A. L.

Abstract High-performance decene-1 oligomerization catalysts based on mesoporous Al-HMS and Al-MCF aluminosilicates modified with an F-4SF sulfonated perfluorinated copolymer have been synthesized. Under batch conditions with a conversion of 90% and in a flow system with a conversion of 83%, these catalysts provide the formation of an oligomerization product with viscosity properties characteristic of poly-α-olefins, the precursors of poly-α-olefin oils.

Modified mesoporous catalysts based on Al-HMS and Al-MCF for the oligomerization of α-olefins

Kulikov, A. B. / Pugacheva, A. A. / Maksimov, A. L.

Abstract High-performance decene-1 oligomerization catalysts based on mesoporous Al-HMS and Al-MCF aluminosilicates modified with an F-4SF sulfonated perfluorinated copolymer have been synthesized. Under batch conditions with a conversion of 90% and in a flow system with a conversion of 83%, these catalysts provide the formation of an oligomerization product with viscosity properties characteristic of poly-α-olefins, the precursors of poly-α-olefin oils.

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Title:

Modified mesoporous catalysts based on Al-HMS and Al-MCF for the oligomerization of α-olefins

Contributors:

Kulikov, A. B. (author) / Pugacheva, A. A. (author) / Maksimov, A. L. (author)

Published in:

Petroleum Chemistry ; 54 ; 426-430

Publication date:

2014-11-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544114060085

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

oligomerization , decene-1 , mesoporous aluminosilicates , perfluorinated copolymer Chemistry , Industrial Chemistry/Chemical Engineering

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