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    Diesel Fraction Hydrotreating in the Presence of Nickel–Tungsten Sulfide Catalyst Particles In Situ Synthesized in Pores of Aromatic Polymers

    New search for: Kulikov, L. A.
    New search for: Maksimov, A. L.
    New search for: Karakhanov, E. A.

    A catalyst based on mixed nickel and tungsten sulfides has been synthesized by the decomposition of the thiosalt [N(n-Bu)4]2[Ni(WS4)2] in pores of a polymer matrix, namely, mesoporous aromatic framework PAF-FC-1. The catalyst has been tested in diesel oil fraction hydrotreating at a hydrogen pressure of 5 MPa and a temperature of 380°C. Reaction products have been analyzed by two-dimensional gas chromatography using a time-of-flight mass detector and a flame ionization detector. It has been shown that the use of the synthesized catalyst provides a decrease in the content of bi- and polycyclic hydrocarbons and a significant decrease in the sulfur compound concentration in oil fractions.

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    Diesel Fraction Hydrotreating in the Presence of Nickel–Tungsten Sulfide Catalyst Particles In Situ Synthesized in Pores of Aromatic Polymers

    New search for: Kulikov, L. A.
    New search for: Maksimov, A. L.
    New search for: Karakhanov, E. A.

    A catalyst based on mixed nickel and tungsten sulfides has been synthesized by the decomposition of the thiosalt [N(n-Bu)4]2[Ni(WS4)2] in pores of a polymer matrix, namely, mesoporous aromatic framework PAF-FC-1. The catalyst has been tested in diesel oil fraction hydrotreating at a hydrogen pressure of 5 MPa and a temperature of 380°C. Reaction products have been analyzed by two-dimensional gas chromatography using a time-of-flight mass detector and a flame ionization detector. It has been shown that the use of the synthesized catalyst provides a decrease in the content of bi- and polycyclic hydrocarbons and a significant decrease in the sulfur compound concentration in oil fractions.

    Access

    Check access
    Check availability in my library
    Order at Subito €

    Diesel Fraction Hydrotreating in the Presence of Nickel–Tungsten Sulfide Catalyst Particles In Situ Synthesized in Pores of Aromatic Polymers

    New search for: Kulikov, L. A.
    New search for: Maksimov, A. L.
    New search for: Karakhanov, E. A.

    A catalyst based on mixed nickel and tungsten sulfides has been synthesized by the decomposition of the thiosalt [N(n-Bu)4]2[Ni(WS4)2] in pores of a polymer matrix, namely, mesoporous aromatic framework PAF-FC-1. The catalyst has been tested in diesel oil fraction hydrotreating at a hydrogen pressure of 5 MPa and a temperature of 380°C. Reaction products have been analyzed by two-dimensional gas chromatography using a time-of-flight mass detector and a flame ionization detector. It has been shown that the use of the synthesized catalyst provides a decrease in the content of bi- and polycyclic hydrocarbons and a significant decrease in the sulfur compound concentration in oil fractions.

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    Title:

    Diesel Fraction Hydrotreating in the Presence of Nickel–Tungsten Sulfide Catalyst Particles In Situ Synthesized in Pores of Aromatic Polymers

    Additional title:

    Pet. Chem.

    Contributors:

    Kulikov, L. A. (author) / Maksimov, A. L. (author) / Karakhanov, E. A. (author)

    Published in:

    Petroleum Chemistry ; 59 ; S66-S71

    Publication date:

    2019-12-01

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544119130103

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    nanoparticles , catalysis , mesoporous materials , hydrogenation Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

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