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Hydrotreating of High-Aromatic Waste of Coke and By-Product Processes in the Presence of in Situ Synthesized Sulfide Nanocatalysts
Abstract The hydrodearomatization and hydrodesulfurization of the coking resin fraction (below 360°C) in the presence of in situ synthesized Ni–W–S catalysts are studied using tungsten hexacarbonyl W(CO)6 and nickel(II) 2-ethylhexanoate Ni(C7H15COO)2 oil-soluble salts at a molar ratio of W: Ni = 1: 2 as precursors for the Ni–W–S catalysts. The resulting catalysts are characterized by transmission electron microscopy; the formation of agglomerates of nanoparticles with an average diameter of 100–200 nm is shown. The optimum temperature for the hydrotreating of the coking resin (380°C) is determined.
Hydrotreating of High-Aromatic Waste of Coke and By-Product Processes in the Presence of in Situ Synthesized Sulfide Nanocatalysts
Abstract The hydrodearomatization and hydrodesulfurization of the coking resin fraction (below 360°C) in the presence of in situ synthesized Ni–W–S catalysts are studied using tungsten hexacarbonyl W(CO)6 and nickel(II) 2-ethylhexanoate Ni(C7H15COO)2 oil-soluble salts at a molar ratio of W: Ni = 1: 2 as precursors for the Ni–W–S catalysts. The resulting catalysts are characterized by transmission electron microscopy; the formation of agglomerates of nanoparticles with an average diameter of 100–200 nm is shown. The optimum temperature for the hydrotreating of the coking resin (380°C) is determined.
Hydrotreating of High-Aromatic Waste of Coke and By-Product Processes in the Presence of in Situ Synthesized Sulfide Nanocatalysts
Sizova, I. A. (author) / Panyukova, D. I. (author) / Maksimov, A. L. (author)
Petroleum Chemistry ; 57 ; 1304-1309
2017-12-01
6 pages
Article (Journal)
Electronic Resource
English
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