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    Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment

    New search for: Zilbershtein, T. M.
    New search for: Nosikov, A. A.
    New search for: Kochnev, A. I.
    New search for: Lipskikh, M. V.
    New search for: Golovko, A. K.

    Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity.

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    Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment

    New search for: Zilbershtein, T. M.
    New search for: Nosikov, A. A.
    New search for: Kochnev, A. I.
    New search for: Lipskikh, M. V.
    New search for: Golovko, A. K.

    Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity.

    Access

    Check access
    Check availability in my library
    Order at Subito €

    Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment

    New search for: Zilbershtein, T. M.
    New search for: Nosikov, A. A.
    New search for: Kochnev, A. I.
    New search for: Lipskikh, M. V.
    New search for: Golovko, A. K.

    Abstract It has been found that the activity of a catalyst for selective oligomerization (trimerization) of ethylene based on a chromium salt and organoaluminum compounds (OACs) can be substantially enhanced by the microwave irradiation of organoaluminum compounds directly prior to mixing them with the chromium salt and a pyrrole ligand. The effects of irradiation conditions and the nature of the reagents used have been studied. The catalyst obtained according to an optimal procedure outperforms known analogs in activity.

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    Title:

    Enhancement of catalytic activity for selective oligomerization of ethylene by microwave treatment

    Contributors:

    Zilbershtein, T. M. (author) / Nosikov, A. A. (author) / Kochnev, A. I. (author) / Lipskikh, M. V. (author) / Golovko, A. K. (author)

    Published in:

    Petroleum Chemistry ; 52 ; 253-260

    Publication date:

    2012-07-01

    Size:

    8 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544112040123

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Microwave Irradiation , Petroleum Chemistry , Microwave Treatment , DEAC , Organoaluminum Compound Chemistry , Industrial Chemistry/Chemical Engineering

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