The Role of <Emphasis Type="Italic">N</Emphasis>-hydroxyphthalimide in the oxidation reactions of alkylarenes with molecular oxygen: Fid-Bau Portal

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The Role of N-hydroxyphthalimide in the oxidation reactions of alkylarenes with molecular oxygen

Opeida, I. A. / Kompanets, M. A. / Kushch, O. V. / Yastrebova, E. G.

Abstract The kinetics of the liquid-phase oxidation of alkylarenes with molecular oxygen in the presence of the initiators azobisisobutyronitrile and benzoyl peroxide and the catalyst N-hydroxyphthalimide (NHPI) was studied. It was found that the rate of oxidation of alkylarenes depended on the partial pressure of oxygen, an effect that is explained by its involvement in the reaction with NHPI resulting in the initiation of the oxidation chain.

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The Role of N-hydroxyphthalimide in the oxidation reactions of alkylarenes with molecular oxygen

Opeida, I. A. / Kompanets, M. A. / Kushch, O. V. / Yastrebova, E. G.

Abstract The kinetics of the liquid-phase oxidation of alkylarenes with molecular oxygen in the presence of the initiators azobisisobutyronitrile and benzoyl peroxide and the catalyst N-hydroxyphthalimide (NHPI) was studied. It was found that the rate of oxidation of alkylarenes depended on the partial pressure of oxygen, an effect that is explained by its involvement in the reaction with NHPI resulting in the initiation of the oxidation chain.

The Role of N-hydroxyphthalimide in the oxidation reactions of alkylarenes with molecular oxygen

Opeida, I. A. / Kompanets, M. A. / Kushch, O. V. / Yastrebova, E. G.

Abstract The kinetics of the liquid-phase oxidation of alkylarenes with molecular oxygen in the presence of the initiators azobisisobutyronitrile and benzoyl peroxide and the catalyst N-hydroxyphthalimide (NHPI) was studied. It was found that the rate of oxidation of alkylarenes depended on the partial pressure of oxygen, an effect that is explained by its involvement in the reaction with NHPI resulting in the initiation of the oxidation chain.

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Title:

The Role of N-hydroxyphthalimide in the oxidation reactions of alkylarenes with molecular oxygen

Contributors:

Opeida, I. A. (author) / Kompanets, M. A. (author) / Kushch, O. V. (author) / Yastrebova, E. G. (author)

Published in:

Petroleum Chemistry ; 49 ; 389-392

Publication date:

2009-09-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544109050090

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Molecular Oxygen , AIBN , Cumene , Petroleum Chemistry , Benzoyl Peroxide Chemistry , Industrial Chemistry/Chemical Engineering

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