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The role of N-hydroxyphthalimide in the reaction mechanism of liquid-phase oxidation of p-cymene
Abstract The reaction of the liquid-phase oxidation of p-cymene to hydroperoxide with a selectivity of up to 95% at a hydrocarbon conversion of 25–30% has been studied at a reaction temperature of 80–120°C in the presence of N-hydroxyphthalimide as the catalyst. The catalytic role of N-hydroxyphthalimide has been substantiated. A kinetic model of the liquid-phase oxidation reaction in the presence of the catalyst N-hydroxyphthalimide has been developed and adequately described.
The role of N-hydroxyphthalimide in the reaction mechanism of liquid-phase oxidation of p-cymene
Abstract The reaction of the liquid-phase oxidation of p-cymene to hydroperoxide with a selectivity of up to 95% at a hydrocarbon conversion of 25–30% has been studied at a reaction temperature of 80–120°C in the presence of N-hydroxyphthalimide as the catalyst. The catalytic role of N-hydroxyphthalimide has been substantiated. A kinetic model of the liquid-phase oxidation reaction in the presence of the catalyst N-hydroxyphthalimide has been developed and adequately described.
The role of N-hydroxyphthalimide in the reaction mechanism of liquid-phase oxidation of p-cymene
Sapunov, V. N. (author) / Koshel’, G. N. (author) / Rumyantseva, Yu. B. (author) / Kurganova, E. A. (author) / Kukushkina, N. D. (author)
Petroleum Chemistry ; 53 ; 171-176
2013-05-01
6 pages
Article (Journal)
Electronic Resource
English
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