Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst: Fid-Bau Portal

Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst

Raskil’dina, G. Z. / Suleimanova, A. M. / Kazakova, A. N. / Grigor’eva, N. G. / Kutepov, B. I. / Zlotskii, S. S.

Abstract The reaction of direct hydroalkoxylation of norbornene in the presence of H-beta zeolite catalyst has been studied. It has been found that the selectivity for exo-alkoxynorbornanes of the reaction of norbornene with monohydric alcohols (saturated, unsaturated, or aromatic) reaches 98% at a conversion of 78–98% of the unsaturated compound. The reaction of norbornene with diols (ethylene glycol and 2-butene-1,4-diol) in the presence of H-beta zeolite affords mono- and diethers, whose yield and ratio can be controlled by varying reaction parameters.

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Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst

Raskil’dina, G. Z. / Suleimanova, A. M. / Kazakova, A. N. / Grigor’eva, N. G. / Kutepov, B. I. / Zlotskii, S. S.

Abstract

Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst

Raskil’dina, G. Z. / Suleimanova, A. M. / Kazakova, A. N. / Grigor’eva, N. G. / Kutepov, B. I. / Zlotskii, S. S.

Abstract

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Title:

Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst

Contributors:

Raskil’dina, G. Z. (author) / Suleimanova, A. M. (author) / Kazakova, A. N. (author) / Grigor’eva, N. G. (author) / Kutepov, B. I. (author) / Zlotskii, S. S. (author)

Published in:

Petroleum Chemistry ; 55 ; 154-162

Publication date:

2015-03-01

Size:

9 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544115020164

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

hydroalkoxylation with alcohols , norbornene , zeolite catalyst Chemistry , Industrial Chemistry/Chemical Engineering

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