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Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins
https://orcid.org/https://orcid.org/0000-0003-4986-0549
https://orcid.org/https://orcid.org/0000-0002-7665-5404
https://orcid.org/https://orcid.org/0000-0001-6386-0006
https://orcid.org/https://orcid.org/0000-0003-4727-954X
A novel catalyst was synthesized by immobilizing a MoO2(acac)2 complex on the surface of a porous aromatic framework functionalized with pyridine-2-carboxaldehyde (PAF-30-NPy). The immobilization was confirmed by IR spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The synthesized catalyst was tested in the epoxidation of cyclohexene, cycloheptene, 1-hexene, 1-octene, styrene, and trans-stilbene. The effects of the solvent type and the oxidant content on the olefin conversion were described. The catalyst reusability was further tested, and its activity was evaluated.
Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins
https://orcid.org/https://orcid.org/0000-0003-4986-0549
https://orcid.org/https://orcid.org/0000-0002-7665-5404
https://orcid.org/https://orcid.org/0000-0001-6386-0006
https://orcid.org/https://orcid.org/0000-0003-4727-954X
A novel catalyst was synthesized by immobilizing a MoO2(acac)2 complex on the surface of a porous aromatic framework functionalized with pyridine-2-carboxaldehyde (PAF-30-NPy). The immobilization was confirmed by IR spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The synthesized catalyst was tested in the epoxidation of cyclohexene, cycloheptene, 1-hexene, 1-octene, styrene, and trans-stilbene. The effects of the solvent type and the oxidant content on the olefin conversion were described. The catalyst reusability was further tested, and its activity was evaluated.
Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins
https://orcid.org/https://orcid.org/0000-0003-4986-0549
https://orcid.org/https://orcid.org/0000-0002-7665-5404
https://orcid.org/https://orcid.org/0000-0001-6386-0006
https://orcid.org/https://orcid.org/0000-0003-4727-954X
A novel catalyst was synthesized by immobilizing a MoO2(acac)2 complex on the surface of a porous aromatic framework functionalized with pyridine-2-carboxaldehyde (PAF-30-NPy). The immobilization was confirmed by IR spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The synthesized catalyst was tested in the epoxidation of cyclohexene, cycloheptene, 1-hexene, 1-octene, styrene, and trans-stilbene. The effects of the solvent type and the oxidant content on the olefin conversion were described. The catalyst reusability was further tested, and its activity was evaluated.
Molybdenum Catalysts Supported on Porous Aromatic Frameworks in Epoxidation of Olefins
Pet. Chem.
Makhova, V. A. (author) / Kulikov, L. A. (author) / Akopyan, A. V. (author) / Karakhanov, E. A. (author)
Petroleum Chemistry ; 64 ; 492-499
2024-04-01
8 pages
Article (Journal)
Electronic Resource
English
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