Hydrodearomatization catalysts based on molybdenum hexacarbonyl Mo(CO)<Subscript>6</Subscript> supported on mesoporous aromatic frameworks: Fid-Bau Portal

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Hydrodearomatization catalysts based on molybdenum hexacarbonyl Mo(CO)6 supported on mesoporous aromatic frameworks

Maksimov, A. L. / Karakhanov, E. A. / Kulikov, L. A. / Terenina, M. V.

Abstract A method for synthesizing fine hydrodearomatization catalysts based on the immobilization of molybdenum carbonyl into the pores of mesoporous aromatic frameworks is proposed. It is shown that the amount of the deposited metal and the average size of the resulting particles depend on the support and the deposition method characteristics. The catalytic activity of the synthesized materials in the hydrogenation of bicyclic hydrocarbons at a hydrogen pressure of 5.0 MPa in a temperature range of 330–500°C is studied using the example of naphthalene, methylnaphthalenes, and biphenyl as model substrates.

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Hydrodearomatization catalysts based on molybdenum hexacarbonyl Mo(CO)6 supported on mesoporous aromatic frameworks

Maksimov, A. L. / Karakhanov, E. A. / Kulikov, L. A. / Terenina, M. V.

Abstract A method for synthesizing fine hydrodearomatization catalysts based on the immobilization of molybdenum carbonyl into the pores of mesoporous aromatic frameworks is proposed. It is shown that the amount of the deposited metal and the average size of the resulting particles depend on the support and the deposition method characteristics. The catalytic activity of the synthesized materials in the hydrogenation of bicyclic hydrocarbons at a hydrogen pressure of 5.0 MPa in a temperature range of 330–500°C is studied using the example of naphthalene, methylnaphthalenes, and biphenyl as model substrates.

Hydrodearomatization catalysts based on molybdenum hexacarbonyl Mo(CO)6 supported on mesoporous aromatic frameworks

Maksimov, A. L. / Karakhanov, E. A. / Kulikov, L. A. / Terenina, M. V.

Abstract A method for synthesizing fine hydrodearomatization catalysts based on the immobilization of molybdenum carbonyl into the pores of mesoporous aromatic frameworks is proposed. It is shown that the amount of the deposited metal and the average size of the resulting particles depend on the support and the deposition method characteristics. The catalytic activity of the synthesized materials in the hydrogenation of bicyclic hydrocarbons at a hydrogen pressure of 5.0 MPa in a temperature range of 330–500°C is studied using the example of naphthalene, methylnaphthalenes, and biphenyl as model substrates.

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Title:

Hydrodearomatization catalysts based on molybdenum hexacarbonyl Mo(CO)6 supported on mesoporous aromatic frameworks

Contributors:

Maksimov, A. L. (author) / Karakhanov, E. A. (author) / Kulikov, L. A. (author) / Terenina, M. V. (author)

Published in:

Petroleum Chemistry ; 57 ; 589-594

Publication date:

2017-07-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544117070076

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

mesoporous materials , nanoheterogeneous catalysis , hydrodearomatization , nanoparticles Chemistry , Industrial Chemistry/Chemical Engineering

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