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Reactivity correlation of alcohols in hydroalkoxycarbonylation and transesterification reactions

Aver’yanov, V. A. / Nosova, N. M. / Batashev, S. A.

Abstract The alcohol reactivity series in competitive cyclohexene hydroalkoxycarbonylation catalyzed by the Pd(PPh3)2Cl2 complex in the presence of various alcohols was obtained: n-BuOH > n-PrOH > iso-BuOH ≥ CH3OH > C2H5OH > C6H11OH > iso-PrOH > C7H7OH. It was shown that this series correlates well with that of alcohol reactivity in the transesterification reaction. A stronger response of the transesterification rate to alcohol structure is caused by a lower reactivity of esters relative to phosphine acylpalladium complexes responsible for ester formation in the hydroalkoxycarbonylation reaction.

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Reactivity correlation of alcohols in hydroalkoxycarbonylation and transesterification reactions

Aver’yanov, V. A. / Nosova, N. M. / Batashev, S. A.

Abstract The alcohol reactivity series in competitive cyclohexene hydroalkoxycarbonylation catalyzed by the Pd(PPh3)2Cl2 complex in the presence of various alcohols was obtained: n-BuOH > n-PrOH > iso-BuOH ≥ CH3OH > C2H5OH > C6H11OH > iso-PrOH > C7H7OH. It was shown that this series correlates well with that of alcohol reactivity in the transesterification reaction. A stronger response of the transesterification rate to alcohol structure is caused by a lower reactivity of esters relative to phosphine acylpalladium complexes responsible for ester formation in the hydroalkoxycarbonylation reaction.

Reactivity correlation of alcohols in hydroalkoxycarbonylation and transesterification reactions

Aver’yanov, V. A. / Nosova, N. M. / Batashev, S. A.

Abstract The alcohol reactivity series in competitive cyclohexene hydroalkoxycarbonylation catalyzed by the Pd(PPh3)2Cl2 complex in the presence of various alcohols was obtained: n-BuOH > n-PrOH > iso-BuOH ≥ CH3OH > C2H5OH > C6H11OH > iso-PrOH > C7H7OH. It was shown that this series correlates well with that of alcohol reactivity in the transesterification reaction. A stronger response of the transesterification rate to alcohol structure is caused by a lower reactivity of esters relative to phosphine acylpalladium complexes responsible for ester formation in the hydroalkoxycarbonylation reaction.

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Title:

Reactivity correlation of alcohols in hydroalkoxycarbonylation and transesterification reactions

Contributors:

Aver’yanov, V. A. (author) / Nosova, N. M. (author) / Batashev, S. A. (author)

Published in:

Petroleum Chemistry ; 46 ; 99-102

Publication date:

2006-03-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544106020058

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Ester , Cyclohexene , C2H5OH , Transesterification , PPh3 Chemistry , Industrial Chemistry/Chemical Engineering

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