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    Hydroalkoxycarbonylation of isobutylene with polyhydric alcohols in the presence of catalytic systems based on palladium compounds and tertiary phosphines

    New search for: Suerbaev, Kh. A.
    New search for: Chepaikin, E. G.
    New search for: Appazov, N. O.
    New search for: Dzhiembaev, B. Zh.

    Abstract The reaction of isobutylene hydroalkoxycarbonylation at low carbon monoxide pressures (≤2.0 MPa) with ethylene glycol and glycerol in the presence of catalytic systems based on Pd and mono- and bidentate organic phosphines has been studied. The effect of different conditions of the reaction in the presence of the Pd(Acac)2-PPh3-TsOH catalyst system on the ratio of the products, mono- and diglycolides (mono-, di-and triglycerides) of isovaleric acid has been investigated. The relative catalytic activity of a number of binary and ternary systems based on synthesized Pd(Acac)2, Pd(PPh3)4, and PdCl2(PPH3)2 complexes has been determined.

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    Hydroalkoxycarbonylation of isobutylene with polyhydric alcohols in the presence of catalytic systems based on palladium compounds and tertiary phosphines

    New search for: Suerbaev, Kh. A.
    New search for: Chepaikin, E. G.
    New search for: Appazov, N. O.
    New search for: Dzhiembaev, B. Zh.

    Abstract The reaction of isobutylene hydroalkoxycarbonylation at low carbon monoxide pressures (≤2.0 MPa) with ethylene glycol and glycerol in the presence of catalytic systems based on Pd and mono- and bidentate organic phosphines has been studied. The effect of different conditions of the reaction in the presence of the Pd(Acac)2-PPh3-TsOH catalyst system on the ratio of the products, mono- and diglycolides (mono-, di-and triglycerides) of isovaleric acid has been investigated. The relative catalytic activity of a number of binary and ternary systems based on synthesized Pd(Acac)2, Pd(PPh3)4, and PdCl2(PPH3)2 complexes has been determined.

    Access

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    Hydroalkoxycarbonylation of isobutylene with polyhydric alcohols in the presence of catalytic systems based on palladium compounds and tertiary phosphines

    New search for: Suerbaev, Kh. A.
    New search for: Chepaikin, E. G.
    New search for: Appazov, N. O.
    New search for: Dzhiembaev, B. Zh.

    Abstract The reaction of isobutylene hydroalkoxycarbonylation at low carbon monoxide pressures (≤2.0 MPa) with ethylene glycol and glycerol in the presence of catalytic systems based on Pd and mono- and bidentate organic phosphines has been studied. The effect of different conditions of the reaction in the presence of the Pd(Acac)2-PPh3-TsOH catalyst system on the ratio of the products, mono- and diglycolides (mono-, di-and triglycerides) of isovaleric acid has been investigated. The relative catalytic activity of a number of binary and ternary systems based on synthesized Pd(Acac)2, Pd(PPh3)4, and PdCl2(PPH3)2 complexes has been determined.

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    Title:

    Hydroalkoxycarbonylation of isobutylene with polyhydric alcohols in the presence of catalytic systems based on palladium compounds and tertiary phosphines

    Contributors:

    Suerbaev, Kh. A. (author) / Chepaikin, E. G. (author) / Appazov, N. O. (author) / Dzhiembaev, B. Zh. (author)

    Published in:

    Petroleum Chemistry ; 52 ; 189-193

    Publication date:

    2012-05-01

    Size:

    5 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544112030127

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Acac , Isobutylene , Petroleum Chemistry , Dppe , Dppm Chemistry , Industrial Chemistry/Chemical Engineering

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