The role of labile products of styrene epoxide conversion in its oxidation in polar acid medium: Fid-Bau Portal

Fachinformationsdienst BAUdigital

A platform for research: civil engineering, architecture and urbanism

The role of labile products of styrene epoxide conversion in its oxidation in polar acid medium

Petrov, L. V. / Solyanikov, V. M.

Abstract Phenylacetaldehyde (PAA) and benzyl alcohol (BAl) are formed in oxygen atmosphere from styrene epoxide in the presence of p- toluenesulfonic acid (TSA) in a solution of 90 vol % tert-butanol with 10 vol % chlorobenzene (BUC). The ratio of the propagation (k 2 ) to the termination (k 6) rate constants has been measured to be k 2/√k 6 = 8.6 × × 10−3 (L/(mol s))1/2 at 343 K by the method of initiated oxidation of PAA in a BUC solution. One of the products of the radical chain PAA oxidation is BA. This reaction leads to BAl accumulation during the conjugated oxidation of PAA with the epoxide in an acid alcohol medium. The contribution of BAl formed to the oxidation is almost unnoticeable.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

The role of labile products of styrene epoxide conversion in its oxidation in polar acid medium

Petrov, L. V. / Solyanikov, V. M.

Abstract Phenylacetaldehyde (PAA) and benzyl alcohol (BAl) are formed in oxygen atmosphere from styrene epoxide in the presence of p- toluenesulfonic acid (TSA) in a solution of 90 vol % tert-butanol with 10 vol % chlorobenzene (BUC). The ratio of the propagation (k 2 ) to the termination (k 6) rate constants has been measured to be k 2/√k 6 = 8.6 × × 10−3 (L/(mol s))1/2 at 343 K by the method of initiated oxidation of PAA in a BUC solution. One of the products of the radical chain PAA oxidation is BA. This reaction leads to BAl accumulation during the conjugated oxidation of PAA with the epoxide in an acid alcohol medium. The contribution of BAl formed to the oxidation is almost unnoticeable.

The role of labile products of styrene epoxide conversion in its oxidation in polar acid medium

Petrov, L. V. / Solyanikov, V. M.

Abstract Phenylacetaldehyde (PAA) and benzyl alcohol (BAl) are formed in oxygen atmosphere from styrene epoxide in the presence of p- toluenesulfonic acid (TSA) in a solution of 90 vol % tert-butanol with 10 vol % chlorobenzene (BUC). The ratio of the propagation (k 2 ) to the termination (k 6) rate constants has been measured to be k 2/√k 6 = 8.6 × × 10−3 (L/(mol s))1/2 at 343 K by the method of initiated oxidation of PAA in a BUC solution. One of the products of the radical chain PAA oxidation is BA. This reaction leads to BAl accumulation during the conjugated oxidation of PAA with the epoxide in an acid alcohol medium. The contribution of BAl formed to the oxidation is almost unnoticeable.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Document information

Title:

The role of labile products of styrene epoxide conversion in its oxidation in polar acid medium

Contributors:

Petrov, L. V. (author) / Solyanikov, V. M. (author)

Published in:

Petroleum Chemistry ; 53 ; 326-330

Publication date:

2013-09-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544113040105

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

styrene epoxide , p-toluenesulfonic acid , phenylacetaldehyde , benzaldehyde , benzyl alcohol , oxidation by molecular oxygen Chemistry , Industrial Chemistry/Chemical Engineering

Similar titles

Trends in oxidation and buildup of conversion products of the hydroquinone–styrene epoxide–p-toluenesulfonic acid ternary system in a polar solution

Petrov, L. V. / Solyanikov, V. M. | Springer Verlag | 2017

Effect of polar solvents on the conversion of styrene epoxide in the presence of p-toluenesulfonic acid

Petrov, L. V. / Psikha, B. L. / Solyanikov, V. M. | Springer Verlag | 2007

Mild oxidation of styrene epoxide in the presence of trace perchloric acid

Petrov, L. V. / Solyanikov, V. M. | Springer Verlag | 2011

Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution

Petrov, L. V. / Spirin, M. G. / Solyanikov, V. M. | Springer Verlag | 2023

Assessment of the competitiveness of the radical and nonradical mechanisms in the acid-catalyzed oxidation of styrene epoxide

Petrov, L. V. / Psikha, B. L. / Solyanikov, V. M. | Springer Verlag | 2009