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Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution
https://orcid.org/https://orcid.org/0000-0001-9598-3748
https://orcid.org/https://orcid.org/0000-0002-3761-1468
https://orcid.org/https://orcid.org/0000-0001-8118-9367
Oxygen uptake by the styrene epoxide (SE)–sulfuric acid (SA) binary system in a solution consisting of 90 vol % tert-butanol and 10 vol % chlorobenzene (BUC solvent) was studied. The equation for the reaction rate as a function of reactant concentrations and the Arrhenius equation for the effective oxidation rate constant are presented. Comparison of the results obtained with the data on oxidation in related binary systems SE–perchloric acid (PCA) and SE–p-toluenesulfonic acid (TSA) shows that the specific features of the oxidation of these systems are determined by the kind of the acid catalyst.
Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution
https://orcid.org/https://orcid.org/0000-0001-9598-3748
https://orcid.org/https://orcid.org/0000-0002-3761-1468
https://orcid.org/https://orcid.org/0000-0001-8118-9367
Oxygen uptake by the styrene epoxide (SE)–sulfuric acid (SA) binary system in a solution consisting of 90 vol % tert-butanol and 10 vol % chlorobenzene (BUC solvent) was studied. The equation for the reaction rate as a function of reactant concentrations and the Arrhenius equation for the effective oxidation rate constant are presented. Comparison of the results obtained with the data on oxidation in related binary systems SE–perchloric acid (PCA) and SE–p-toluenesulfonic acid (TSA) shows that the specific features of the oxidation of these systems are determined by the kind of the acid catalyst.
Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution
https://orcid.org/https://orcid.org/0000-0001-9598-3748
https://orcid.org/https://orcid.org/0000-0002-3761-1468
https://orcid.org/https://orcid.org/0000-0001-8118-9367
Oxygen uptake by the styrene epoxide (SE)–sulfuric acid (SA) binary system in a solution consisting of 90 vol % tert-butanol and 10 vol % chlorobenzene (BUC solvent) was studied. The equation for the reaction rate as a function of reactant concentrations and the Arrhenius equation for the effective oxidation rate constant are presented. Comparison of the results obtained with the data on oxidation in related binary systems SE–perchloric acid (PCA) and SE–p-toluenesulfonic acid (TSA) shows that the specific features of the oxidation of these systems are determined by the kind of the acid catalyst.
Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution
Pet. Chem.
Petrov, L. V. (author) / Spirin, M. G. (author) / Solyanikov, V. M. (author)
Petroleum Chemistry ; 63 ; 421-427
2023-04-01
7 pages
Article (Journal)
Electronic Resource
English
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