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Dichlorocarbenation of conjugated diene hydrocarbons
Abstract Partial and complete dichlorocarbenation of conjugated diene hydrocarbons in the presence of the phase-transfer catalyst catamine AB has been studied. It has been shown that at the initial stages of the process (conversion of the reactant olefins below 30%), alkenyl-gem-dichlorocyclopropanes are the main products. In the case of complete carbenation, corresponding bicyclic structures are formed. The structures of the resulting stereoisomers have been described in detail using 1H and 13С NMR methods. The relative reactivity of the initial dienes has been determined using a method of competitive kinetics.
Dichlorocarbenation of conjugated diene hydrocarbons
Abstract Partial and complete dichlorocarbenation of conjugated diene hydrocarbons in the presence of the phase-transfer catalyst catamine AB has been studied. It has been shown that at the initial stages of the process (conversion of the reactant olefins below 30%), alkenyl-gem-dichlorocyclopropanes are the main products. In the case of complete carbenation, corresponding bicyclic structures are formed. The structures of the resulting stereoisomers have been described in detail using 1H and 13С NMR methods. The relative reactivity of the initial dienes has been determined using a method of competitive kinetics.
Dichlorocarbenation of conjugated diene hydrocarbons
Raskil’dina, G. Z. (author) / Borisova, Yu. G. (author) / Yanybin, V. M. (author) / Zlotskii, S. S. (author)
Petroleum Chemistry ; 57 ; 278-283
2017-03-01
6 pages
Article (Journal)
Electronic Resource
English
Design of Novel Conjugated Polymer Poly(cyclopenta-1,3-Diene)
| British Library Online Contents | 2011