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    Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system

    New search for: Suerbaev, H. A.
    New search for: Chepajkin, E. G.
    New search for: Dzhiembaev, B. Zh.
    New search for: Appazov, I. O.
    New search for: Abyzbekova, G. M.

    Abstract The reaction of isobutylene hydroalcoxycarbonylation with CO and polyhydric alcohols (ethylene glycol, glycerol) in the presence of the catalytic system Pd(aacac)2-PPh3-TsOH has been investigated. It was found that carbonylation of isobutylene with CO in the presence of ethylene glycol yields a mixture of mono-and diglycol esters of isovaleric acid, irrespective of the initial reactant ratio. During the hydroalcoxycarbonylation of isobutylene with glycerol, either mono- and di- or mono-, di-, and triglycerides of isovaleric acid are formed depending on the reactant ratio.

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    Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system

    New search for: Suerbaev, H. A.
    New search for: Chepajkin, E. G.
    New search for: Dzhiembaev, B. Zh.
    New search for: Appazov, I. O.
    New search for: Abyzbekova, G. M.

    Abstract The reaction of isobutylene hydroalcoxycarbonylation with CO and polyhydric alcohols (ethylene glycol, glycerol) in the presence of the catalytic system Pd(aacac)2-PPh3-TsOH has been investigated. It was found that carbonylation of isobutylene with CO in the presence of ethylene glycol yields a mixture of mono-and diglycol esters of isovaleric acid, irrespective of the initial reactant ratio. During the hydroalcoxycarbonylation of isobutylene with glycerol, either mono- and di- or mono-, di-, and triglycerides of isovaleric acid are formed depending on the reactant ratio.

    Access

    Check access
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    Order at Subito €

    Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system

    New search for: Suerbaev, H. A.
    New search for: Chepajkin, E. G.
    New search for: Dzhiembaev, B. Zh.
    New search for: Appazov, I. O.
    New search for: Abyzbekova, G. M.

    Abstract The reaction of isobutylene hydroalcoxycarbonylation with CO and polyhydric alcohols (ethylene glycol, glycerol) in the presence of the catalytic system Pd(aacac)2-PPh3-TsOH has been investigated. It was found that carbonylation of isobutylene with CO in the presence of ethylene glycol yields a mixture of mono-and diglycol esters of isovaleric acid, irrespective of the initial reactant ratio. During the hydroalcoxycarbonylation of isobutylene with glycerol, either mono- and di- or mono-, di-, and triglycerides of isovaleric acid are formed depending on the reactant ratio.

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    Title:

    Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system

    Contributors:

    Suerbaev, H. A. (author) / Chepajkin, E. G. (author) / Dzhiembaev, B. Zh. (author) / Appazov, I. O. (author) / Abyzbekova, G. M. (author)

    Published in:

    Petroleum Chemistry ; 47 ; 345-347

    Publication date:

    2007-09-01

    Size:

    3 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544107050064

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Acac , Monoglyceride , Isobutylene , Diglyceride , Petroleum Chemistry Chemistry , Industrial Chemistry/Chemical Engineering

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