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    Effects of Bulky Substituents on Transport Properties of Membrane Gas Separation Materials

    New search for: Yampolksii, Yu. P.
    New search for: Banerjee, S.

    Abstract In this review membrane gas separation properties of two groups of glassy polymers are considered and compared. The first group comprises highly permeable polymers with large free volume. They contains bulky substituents of the structure MR3, where M = Si, Ge, C, and R = Me, Et, Ph. The second group is represented by polycondensation materials (polyamides, polyimides etc.) with various bulky side groups. It was noted that introduction of such substituents into various main chains of polymers of both groups results in increases in gas permeability, free volume and diffusivity. Robeson diagrams for both cases are considered.

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    Effects of Bulky Substituents on Transport Properties of Membrane Gas Separation Materials

    New search for: Yampolksii, Yu. P.
    New search for: Banerjee, S.

    Abstract In this review membrane gas separation properties of two groups of glassy polymers are considered and compared. The first group comprises highly permeable polymers with large free volume. They contains bulky substituents of the structure MR3, where M = Si, Ge, C, and R = Me, Et, Ph. The second group is represented by polycondensation materials (polyamides, polyimides etc.) with various bulky side groups. It was noted that introduction of such substituents into various main chains of polymers of both groups results in increases in gas permeability, free volume and diffusivity. Robeson diagrams for both cases are considered.

    Access

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    Effects of Bulky Substituents on Transport Properties of Membrane Gas Separation Materials

    New search for: Yampolksii, Yu. P.
    New search for: Banerjee, S.

    Abstract In this review membrane gas separation properties of two groups of glassy polymers are considered and compared. The first group comprises highly permeable polymers with large free volume. They contains bulky substituents of the structure MR3, where M = Si, Ge, C, and R = Me, Et, Ph. The second group is represented by polycondensation materials (polyamides, polyimides etc.) with various bulky side groups. It was noted that introduction of such substituents into various main chains of polymers of both groups results in increases in gas permeability, free volume and diffusivity. Robeson diagrams for both cases are considered.

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    Title:

    Effects of Bulky Substituents on Transport Properties of Membrane Gas Separation Materials

    Contributors:

    Yampolksii, Yu. P. (author) / Banerjee, S. (author)

    Published in:

    Petroleum Chemistry ; 57 ; 1195-1206

    Publication date:

    2017-12-01

    Size:

    12 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544117130114

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    highly permeable polymers , polycondensation materials , permeability , diffusion , solubility , selectivity of gas separation , free volume Chemistry , Industrial Chemistry/Chemical Engineering

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