Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers: Fid-Bau Portal

Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers

Rakhmanov, E. V. / Baranova, S. V. / Wang, Zixiao / Tarakanova, A. V. / Kardashev, S. V. / Akopyan, A. V. / Naranov, E. R. / Oshchepkov, M. S. / Anisimov, A. V.

Abstract

Abstract Hydrogen peroxide oxidative desulfurization of model diesel fuel mixtures in the presence of azacrown ethers and their complexes with niobium pentachloride at 40–80°C has been studied. It has been found that the use of complexes of azacrown ethers with NbCl5 leads to a decrease in the total sulfur content in the model mixtures to 13% of the initial amount. The structure of the azacrown ether used has little effect on the extent of desulfurization of the model mixture.

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Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers

Rakhmanov, E. V. / Baranova, S. V. / Wang, Zixiao / Tarakanova, A. V. / Kardashev, S. V. / Akopyan, A. V. / Naranov, E. R. / Oshchepkov, M. S. / Anisimov, A. V.

Abstract

Hydrogen peroxide oxidative desulfurization of model diesel mixtures using azacrown ethers

Rakhmanov, E. V. / Baranova, S. V. / Wang, Zixiao / Tarakanova, A. V. / Kardashev, S. V. / Akopyan, A. V. / Naranov, E. R. / Oshchepkov, M. S. / Anisimov, A. V.