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Oxidative desulfurization of catalytically cracked gasoline with hydrogen peroxide

Rakhmanov, E. V. / Anisimov, A. V. / Tarakanova, A. V. / Baleeva, N. S. / Guluzade, D.

Abstract Hydrogen peroxide desulfurization at 50°C of a catalytically cracked gasoline fraction containing methyl- and dimethylthiophenes and traces of benzothiophene and dibenzothiophene and boiling in the range of IBP-70°C in the presence of transition metal compounds Na2MoO4, Na2WO4, VOSO4, and [Cu(NH3)4]CO3 followed by adsorption on alumina has been studied. The successive oxidation of the hydrocarbon fraction in the presence of the copper and molybdenum compounds under phase transfer conditions ensures the removal of up to 96% of total sulfur.

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Oxidative desulfurization of catalytically cracked gasoline with hydrogen peroxide

Rakhmanov, E. V. / Anisimov, A. V. / Tarakanova, A. V. / Baleeva, N. S. / Guluzade, D.

Abstract

Oxidative desulfurization of catalytically cracked gasoline with hydrogen peroxide

Rakhmanov, E. V. / Anisimov, A. V. / Tarakanova, A. V. / Baleeva, N. S. / Guluzade, D.

Abstract

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Title:

Oxidative desulfurization of catalytically cracked gasoline with hydrogen peroxide

Contributors:

Rakhmanov, E. V. (author) / Anisimov, A. V. (author) / Tarakanova, A. V. (author) / Baleeva, N. S. (author) / Guluzade, D. (author)

Published in:

Petroleum Chemistry ; 53 ; 201-204

Publication date:

2013-05-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544113030080

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

desulfurization , hydrogen peroxide , gasoline , catalytic cracking , peroxo complexes , transition metals Chemistry , Industrial Chemistry/Chemical Engineering

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