Selective Hydrogenation of Phenol Using a Ni<sub>2</sub>P Catalyst Supported on Mesoporous Polymeric Nanospheres: Fid-Bau Portal

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Selective Hydrogenation of Phenol Using a Ni₂P Catalyst Supported on Mesoporous Polymeric Nanospheres

Shakirov, I. I. / Boronoev, M. P. / Kardashev, S. V. / Putilin, F. N. / Karakhanov, E. A.

The paper describes the synthesis of a Ni₂P-NSMR catalyst based on nickel phosphides supported on a nanospherical mesoporous resorcinol–formaldehyde polymer. The catalyst was tested in the hydrogenation of phenol at 220, 270, and 320°C and at a hydrogen pressure of 6.0 MPa. The cyclohexanone selectivity and phenol conversion in the presence of Ni₂P nanoparticles supported on the mesoporous polymer amounted to 92 and 17%, respectively, compared to 80 and 13% in the presence of unsupported Ni₂P nanoparticles.

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Selective Hydrogenation of Phenol Using a Ni₂P Catalyst Supported on Mesoporous Polymeric Nanospheres

Shakirov, I. I. / Boronoev, M. P. / Kardashev, S. V. / Putilin, F. N. / Karakhanov, E. A.

The paper describes the synthesis of a Ni₂P-NSMR catalyst based on nickel phosphides supported on a nanospherical mesoporous resorcinol–formaldehyde polymer. The catalyst was tested in the hydrogenation of phenol at 220, 270, and 320°C and at a hydrogen pressure of 6.0 MPa. The cyclohexanone selectivity and phenol conversion in the presence of Ni₂P nanoparticles supported on the mesoporous polymer amounted to 92 and 17%, respectively, compared to 80 and 13% in the presence of unsupported Ni₂P nanoparticles.

Selective Hydrogenation of Phenol Using a Ni₂P Catalyst Supported on Mesoporous Polymeric Nanospheres

Shakirov, I. I. / Boronoev, M. P. / Kardashev, S. V. / Putilin, F. N. / Karakhanov, E. A.

The paper describes the synthesis of a Ni₂P-NSMR catalyst based on nickel phosphides supported on a nanospherical mesoporous resorcinol–formaldehyde polymer. The catalyst was tested in the hydrogenation of phenol at 220, 270, and 320°C and at a hydrogen pressure of 6.0 MPa. The cyclohexanone selectivity and phenol conversion in the presence of Ni₂P nanoparticles supported on the mesoporous polymer amounted to 92 and 17%, respectively, compared to 80 and 13% in the presence of unsupported Ni₂P nanoparticles.

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Title:

Selective Hydrogenation of Phenol Using a Ni₂P Catalyst Supported on Mesoporous Polymeric Nanospheres

Additional title:

Pet. Chem.

Contributors:

Shakirov, I. I. (author) / Boronoev, M. P. (author) / Kardashev, S. V. (author) / Putilin, F. N. (author) / Karakhanov, E. A. (author)

Published in:

Petroleum Chemistry ; 61 ; 1111-1117

Publication date:

2021-10-01

Size:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544121100042

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

mesoporous polymer , nanospheres , nickel phosphides , phenol , hydrogenation Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

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