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Ruthenium- and Palladium-Containing Catalysts Based on Mesoporous Polymer Nanospheres in Guaiacol Hydrogenation
https://orcid.org/https://orcid.org/0000-0003-2029-693X
https://orcid.org/https://orcid.org/0000-0001-6129-598X
https://orcid.org/https://orcid.org/0000-0002-0797-0611
https://orcid.org/https://orcid.org/0000-0001-9297-4950
https://orcid.org/https://orcid.org/0000-0003-4727-954X
Catalysts Pd-NSMR and Ru-NSMR based on palladium and ruthenium nanoparticles deposited on a nanospherical mesoporous resorcinol-formaldehyde polymer are synthesized. It is shown that the average size of polymer particles is 220–250 nm and the average size of palladium and ruthenium nanoparticles is 7.2 and 2.2 nm, respectively. The catalysts are tested in guaiacol hydrogenation at a temperature of 200°С and a hydrogen pressure of 4.0 MPa. It is demonstrated that the ruthenium catalyst shows higher activity in guaiacol hydrogenation.
Ruthenium- and Palladium-Containing Catalysts Based on Mesoporous Polymer Nanospheres in Guaiacol Hydrogenation
https://orcid.org/https://orcid.org/0000-0003-2029-693X
https://orcid.org/https://orcid.org/0000-0001-6129-598X
https://orcid.org/https://orcid.org/0000-0002-0797-0611
https://orcid.org/https://orcid.org/0000-0001-9297-4950
https://orcid.org/https://orcid.org/0000-0003-4727-954X
Catalysts Pd-NSMR and Ru-NSMR based on palladium and ruthenium nanoparticles deposited on a nanospherical mesoporous resorcinol-formaldehyde polymer are synthesized. It is shown that the average size of polymer particles is 220–250 nm and the average size of palladium and ruthenium nanoparticles is 7.2 and 2.2 nm, respectively. The catalysts are tested in guaiacol hydrogenation at a temperature of 200°С and a hydrogen pressure of 4.0 MPa. It is demonstrated that the ruthenium catalyst shows higher activity in guaiacol hydrogenation.
Ruthenium- and Palladium-Containing Catalysts Based on Mesoporous Polymer Nanospheres in Guaiacol Hydrogenation
https://orcid.org/https://orcid.org/0000-0003-2029-693X
https://orcid.org/https://orcid.org/0000-0001-6129-598X
https://orcid.org/https://orcid.org/0000-0002-0797-0611
https://orcid.org/https://orcid.org/0000-0001-9297-4950
https://orcid.org/https://orcid.org/0000-0003-4727-954X
Catalysts Pd-NSMR and Ru-NSMR based on palladium and ruthenium nanoparticles deposited on a nanospherical mesoporous resorcinol-formaldehyde polymer are synthesized. It is shown that the average size of polymer particles is 220–250 nm and the average size of palladium and ruthenium nanoparticles is 7.2 and 2.2 nm, respectively. The catalysts are tested in guaiacol hydrogenation at a temperature of 200°С and a hydrogen pressure of 4.0 MPa. It is demonstrated that the ruthenium catalyst shows higher activity in guaiacol hydrogenation.
Ruthenium- and Palladium-Containing Catalysts Based on Mesoporous Polymer Nanospheres in Guaiacol Hydrogenation
Pet. Chem.
Shakirov, I. I. (author) / Boronoev, M. P. (author) / Zolotukhina, A. V. (author) / Maximov, A. L. (author) / Karakhanov, E. A. (author)
Petroleum Chemistry ; 60 ; 1136-1140
2020-10-01
5 pages
Article (Journal)
Electronic Resource
English
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